CommunicationThe synthesis and X-ray crystal structure of molybdenum oxomethoxide [MoO(OMe)4]2
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Cited by (37)
The use of sacrificial anodes for the electrochemical synthesis of metallic complexes
2015, Coordination Chemistry ReviewsCitation Excerpt :So, a number of syntheses of tin oxoalkoxy-complexes with general formula [Sn6(OR)4O4] (R = Me, Et, Pri) were carried out; i.e. the molecular structure of the Sn(II) complex [Sn6(OEt)4O4] [55] (Fig. 5, left) reminds that reported for SnO [158,159]. The synthesis of [MoO(OMe)4]2 was carried out by electrochemical oxidation of a molybdenum anode in a methanol solution of LiCl [160]. The X-ray diffraction studies showed the structure consists of dimeric [MoO(OMe)3(μ-OMe)]2 molecules.
Methanolysis of MoCl<inf>5</inf> in the presence of different alkaline agents; Molecular structures of the polynuclear molybdenum(V) methoxides and electron charge density distribution from X-ray diffraction study of the new K-Mo cluster
2014, PolyhedronCitation Excerpt :Eq. (2) shows the overall reaction stoichiometry. Since the reaction medium lacks oxygen and water, we believe the formation of oxo complexes was mainly due to the propensity of the initially formed molybdenum alkoxides to decomposition with elimination of ethers [42–47]. This is evidenced by the high yield and good reproducibility of the experiments.
Alkoxides and Alkoxosynthesis
2013, Comprehensive Inorganic Chemistry II (Second Edition): From Elements to ApplicationsSupported Re and Mo oxides prepared using binuclear precursors: Synthesis and characterization
2004, Journal of Molecular Catalysis A: Chemical
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Present address: Laboratoire de Chimie Moléculaire, Université de Nice, Parc Valrose, 06108 Nice Cedex 2, France.