Cooperative effect between two metal centres in hydroformylation: Routes towards heterobimetallic catalysis
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Investigation on the reactivity of tetranuclear Group 7/8 mixed-metal clusters toward triphenylphosphine
2018, PolyhedronCitation Excerpt :The triruthenium wing of the butterfly in 5 [Ru(1)Ru(2) 2.8971(9), Ru(1)Ru(3) 2.7551(9), Ru(2)Ru(3) 2.8647(10) Å] are slightly bigger than that in the parent cluster 2 [Ru(1)Ru(2) 2.841(1), Ru(1)Ru(3) 2.760(1), Ru(2)Ru(3) 2.847(1) Å] [16] which can be explained as a consequences of carbonyl substitution by phosphine. The interplanar angle of the butterfly in 5 is 161.1° which is slightly greater than that observed in the parent cluster 2 (159.5°) [16] and the RuP bond distance of 2.3827(15) Å found in 5 is within the range reported in literature [9,26–28]. The ReN [2.190(5) Å] and RuS [2.3796(16) and 2.3776(16) Å] bond distances are very close to those observed in the parent cluster 2 [ReN 2.189(7) Å and RuS 2.380(3) Å].
A potential refinery process of light-light naphtha olefins conversion to valuable oxygenated products in aqueous media - Part 1: Biphasic hydroformylation
2013, FuelCitation Excerpt :TPPTS was prepared in 1974 by modification of TPPMS (TPPMS = (3-sulfonatophenyl) diphenyl phosphine sodium salt) synthesis [2,7]. The high solubility of TPPTS in water (more than 1200 g l−1) is due to the introduction of highly polar sulfonate groups in the three phenyl rings attached to phosphorus (Scheme 1) and allows the hydroformylation to proceed in a two-phase system with the reaction products to form an insoluble organic phase, free from Rh/TPPTS catalytic system [8,9]. Rh/TPPTS complexes have been reported as effective catalytic systems for the hydroformylation of mixtures of olefines.
Hydroformylation of oct-1-ene catalyzed by dinuclear gem-dithiolato-bridged rhodium(I) complexes and phosphorus donor ligands
2009, Journal of Molecular Catalysis A: Chemical