Crystal structures of the dicyclohexyl-(18-crown-6) uranyl perchlorate complex and of its hydrolysis product
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2016, PolyhedronCitation Excerpt :The same motif is present in structure (c) in Fig. 8, except that in this case four uranyl groups surround two oxide ions, each oxide being surrounded by three uranyl groups. This structure is based on one reported [52], which resembles the structure for [(UO2)4O2(OH)3]+ shown, except that two coordinated water molecules are replaced by neutral oxygen donors from complex amide molecules. Again, the motif of two oxides surrounded by four uranyl groups, as shown in structure (c) occurs quite frequently in the CSD, with examples where coordinated waters or bridging hydroxides are replaced by chlorides or N bonding thiocyanates [53,54].
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