Phenanthroline complexes of the d10 metals nickel(0), zinc(II) and silver(I)—comparison to copper(I) species
References (21)
- et al.
Arch. Biochem. Biophys.
(1995) Pure Appl. Chem.
(1975)- et al.
Inorg. Chem.
(1995) J. Med. Chem.
(1995)- et al.
Science
(1996) - et al.
Science
(1996) - et al.
J. Am. Chem. Soc.
(1996) - et al.
J. Am. Chem. Soc.
(1995) - et al.
Prog. Inorg. Chem.
(1995)
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Binding profile of a mixed-ligand silver(I) complex with DNA and Topoisomerase I
2023, Computational Biology and ChemistryCu(I) coordination by N,N,N’,N’-tetra(di-ortho-anisylphosphanylmethyl) ethylene and propylene diamine: First example of a sandwiched CuCl-tetramer
2021, Inorganica Chimica ActaCitation Excerpt :The conformation of the six-membered Cu(I) metallacycle can be best described with a boat conformation, where Cu(1) and N(1) deviate by 0.388 and 0.785 Å, respectively, from the plane defined by P(1), P(2), C(2) and C(3). Compound 1b reacted in CH2Cl2 in the presence of excess [NiCl2(DME)] to give the Cu(I) cluster 2 (Scheme 1C) as crystalline compound along with the known dimer Ni(II) compound of the formula [Ni2Cl4(neocuproine)] (i.e. a single crystal structure analysis and a UV–Vis spectrum, Fig. S2, confirmed its formation [37,38]). Compound 2, which exhibited a low solubility in organic solvents, showed one singlet at −17.9 ppm in the 31P{1H} NMR spectrum, while the 1H NMR spectrum showed two sets of NMR signals assigned to two different L2 ligands.
Exploring the cytotoxic activity of new phenanthroline salicylaldimine Zn(II) complexes
2019, Journal of Inorganic BiochemistryBinding interaction of a heteroleptic silver(I) complex with DNA: A joint experimental and computational study
2019, International Journal of Biological MacromoleculesCitation Excerpt :The density functional theory (DFT) analysis has been applied to obtain the optimized molecular structure. The bis-chelated Ag(I) complexes with N,N-chelating ligands such as 1,10-phenanthroline [50], 4,5-diazaflourene-9-one [51], 1,10-phenanthroline-5,6-dione [52] and N-(4,5-diazafluoren-9-ylidene)aniline [29,30] have been investigated with various geometries such as pseudo square-planar, pseudo-tetrahedral, and distorted tetragonal pyramid structures. For our newly synthesized Ag(I) complex, the obtained CHN elemental analysis data has confirmed the proposed formula and the purity of the resultant complex.
Multispectroscopic DNA-Binding studies and antimicrobial evaluation of new mixed-ligand Silver(I) complex and nanocomplex: A comparative study
2018, Journal of Molecular StructureCitation Excerpt :Previously, the fully characterized dian ligand has been reported in literature [39] which confirms a nearly planar 4,5- diazafluorenylidene unit by a dihedral angle of 75.75 (3)° with respect to the phenyl ring. Phen-type ligands like 1,10-phenanthroline [45], 2,9-Dimethyl-1,10-Phenanthroline [46], 4,5-diazaflourene [47], 1,10-phenanthroline-5,6-dione [26] and N-(4,5-diazafluoren-9-ylidene)aniline [48] in coordination with Ag(I) have formed different geometries such as pseudo square-planar, distorted tetragonal pyramid, and pseudo-tetrahedral structures. The probable structure of our complex can be proposed using the analytical and spectroscopic data accompany with the mode of the biological activity.