Provenance of Cape Supergroup sediments and timing of Cape Fold Belt orogenesis: Constraints from high-precision 40Ar/39Ar dating of muscovite
Graphical abstract
Introduction
The Cape Fold Belt (CFB) is a Permian, low-metamorphic grade, fold and thrust belt that extends ~1300 km along the western and southern coastal margins of southern Africa. It incorporates Neoproterozoic to Cambrian metasediments and Cape Granite Suite igneous rocks of the Saldania Belt, lower to mid-Palaeozoic siliciclastic sediments of the Cape Supergroup, and upper Palaeozoic to lower Mesozoic strata of the overlying Karoo Supergroup (Hälbich, 1983). The CFB is considered a central component of a larger Permian Gondwanide orogenic belt flanking the margin of southwestern Gondwana, extending from the Sierra de la Ventana Fold Belt in Argentina, across southern Africa, and continuing east through the Falkland (Malvinas) Islands and Ellsworth-Whitmore Mountains of Antarctica (Du Toit, 1937; Curtis and Hyam, 1998; Rapela et al., 2003; Lindeque et al., 2011; Pángaro and Ramos, 2012; Fig. 1). However, the relationship of the CFB to other terranes in this Permian orogenic belt, the provenance of the CFB sediments and the timing of regional deformation are poorly constrained, thus hampering efforts to construct a coherent tectonic and structural model for the region.
The Cape Supergroup is a passive margin sedimentary succession of basal quartzites overlain by interbedded sandstone, siltstone and shale units (Thamm and Johnson, 2006). Deposition of the Cape Supergroup within the Cape Basin is estimated to have occurred between ca. 510 and 350 Ma, based on palaeontological evidence and U-Pb detrital zircon ages (Broquet, 1992; Miller et al., 2016a, Miller et al., 2016b; Gess, 2016). U-Pb detrital zircon provenance studies suggest the Cape Supergroup is largely derived from the adjacent Mesoproterozoic Namaqua-Natal Metamorphic Belt (NNMB) and Pan-African and Brasiliano orogenic terranes (Fourie et al., 2011; Naidoo et al., 2013; Miller et al., 2016a, Miller et al., 2016b), with lesser contributions from Ordovician South American sources (Fourie et al., 2011; Ramos et al., 2014). However, further provenance investigations are required to confirm a South American source.
Current constraints on the timing of CFB orogenesis rely on a handful of limited 40Ar/39Ar studies. The first 40Ar/39Ar age constraint for CFB orogenesis was provided by Gentle et al. (1978), who produced an age of 248 ± 2 Ma. Subsequent 40Ar/39Ar studies by Hälbich et al. (1983) and Gresse et al. (1992) suggested that deformation progressed via a series of tectonic pulses within an 80 m.y. period between ~300 and 220 Ma. More recently, Hansma et al. (2015) carried out 40Ar/39Ar experiments on single muscovite grains and bulk muscovite aliquots, and proposed bimodal CFB orogenesis at ca. 275–260 Ma and ca. 255–245 Ma.
A preliminary high precision 40Ar/39Ar dating study by Blewett and Phillips (2016) revealed a clustering of muscovite ages at 253 ± 2 Ma (2σ), which was interpreted as the main/final phase of CFB deformation. However, these ages were confined to three samples from only two locations. Ages >440 Ma reported in this study were interpreted as detrital ages consistent with sediment contributions from Pan-African terranes. At the same time, a large number of grains yielded intermediate apparent ages ranging from 255 and 440 Ma; these results were ascribed to varying degrees of argon loss from older detrital grains and/or the presence of intergrown detrital/neocrystallised mica grains.
The aims of this study are to provide new insights into the provenance of sediments in the Cape Basin and improve constraints on the timing of CFB Orogenesis. This study presents 40Ar/39Ar data for muscovite grains from 27 samples collected in a series of structurally controlled traverses across the CFB. The age results of this study are combined with those of Blewett and Phillips (2016), providing a combined 40Ar/39Ar dataset of over 400 muscovite ages from 41 Cape Supergroup samples across the southern CFB branch. These data were complemented by detailed field observations, documentation of micro-structural features, and muscovite mineral chemistry. The latter information permitted the selection of samples with the greatest potential for defining either sedimentary provenance or constraining the age of CFB deformation.
Section snippets
Geological background
The Cape Supergroup sediments that dominate outcrop within the CFB accumulated in a wedge-shaped basin that may have formed by tectonic inversion and subsequent extension of the Pre-Cambrian basement during the Ordovician (Tankard et al., 1982; Broquet, 1992; Cole, 1992; Thamm and Johnson, 2006; Fig. 1). The basement of the Cape Basin comprises metamorphic rocks of the Mesoproterozoic Namaqua-Natal Belt (NNMB; 1200–1000 Ma; Eglington, 2006), Neoproterozoic to Cambrian Saldania Belt
Sample collection
A total of 93 samples examined in the current study were collected from the more intensely deformed southern branch of the CFB, and from several stratigraphic groups to allow for regional comparisons (Fig. 2). The samples were collected from road cuttings transecting the Cape Supergroup. Relatively undeformed outcrops, exhibiting minimal cleavage development and predicted to yield mainly detrital material, were sampled to investigate sedimentary provenance. Conversely, in order to investigate
Analytical methods
A total of 56 petrographic thin sections were prepared from samples containing visible micas and minimal weathering. The sections were inspected by optical microscopy to characterize mineralogical and textural variations within variously deformed samples. A representative selection of samples (n = 10) containing a range of mica types (i.e. neocrystallised, detrital, and recrystallised detrital grains) were examined using scanning electron microscopy (SEM) backscatter (BSE) imaging to
Petrographic observations
Representative petrographic descriptions of samples selected for 40Ar/39Ar analyses are described here. These descriptions illustrate the range of mica textures and mica generations in samples of variously deformed outcrops. In general, the Cape Supergroup samples are dominated by quartz, with lesser K-feldspar, plagioclase, and muscovite. Rutile, hematite, zircon, monazite and apatite are present as accessory minerals.
Samples collected from relatively undeformed areas, for their potential to
Major element mineral chemistry
Electron microprobe (EMP) major-element compositional analyses of a representative range of mica textures and generations from ten samples are summarised below (Fig. 10), with the complete dataset provided in Supplementary Table 1. EMP analyses of neocrystallised micas, characterized as finely crystalline micas that form foliations and cleavage domains (e.g. Fig. 7d ‘B’; Fig. 9h and j), produced major element compositions resembling ideal octahedral muscovite. These micas contain high K+
40Ar/39Ar dating of Cape Supergroup micas
40Ar/39Ar two-step heating experiments were performed on 231 muscovite grains from 27 Cape Supergroup samples. The age results from these analyses are summarised in Fig. 10, Fig. 11, Fig. 12. As this study is an extension of the preliminary work by Blewett and Phillips (2016), these 40Ar/39Ar age results are also included in the figures (n = 172). Following removal of data (n = 150 grains) where argon yields were low in the fusion steps (40Ar < 100 fA), or where the radiogenic argon signal was
Discussion
The wide range in 40Ar/39Ar muscovite ages (248.0 ± 0.2 Ma to 900.0 ± 4.4 Ma) indicates the presence of a variable mix of detrital, neocrystallised and composite micas in the Cape Fold Belt (CFB) samples analysed. The consistency of muscovite ages from samples PEOU1 (Baviaanskloof Formation, Table Mountain Group), OULS6A (Hex River Formation, Bokkeveld Group), and GT6 (Witpoort Formation, Witteberg Group) (Fig. 13A) from relatively undeformed outcrops, suggests that fusion ages >465 Ma should
Conclusions
40Ar/39Ar analyses of 253 individual muscovite grains from 39 Cape Supergroup samples yield a spread of apparent ages ranging from 248.0 ± 0.2 Ma to 900.0 ± 4.4 Ma. Grains older than 465 Ma are deemed to be of detrital origin, with the presence of >730 Ma and 650–500 Ma aged muscovite grains suggesting sedimentary inputs from the Mesoproterozoic NNMB, and Neoproterozoic Pan-African/Brasiliano-aged terranes of western Gondwana. This is in agreement with the findings of previous U-Pb detrital
Acknowledgements
The authors thank Maarten de Wit, Bastien Linol, and Warren Miller of Nelson Mandela University for their guidance and assistance in the field. We are grateful to Stan Szcezepanski for his support in the 40Ar/39Ar Laboratory, and Graham Hutchinson for his technical assistance with SEM and EMP analyses at the University of Melbourne. This manuscript benefitted from the constructive reviews by two anonymous referees, and the editorial handling of Ian Somerville.
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