The influences of the packing ligand on spin state and magnetic interactions in new oxalates with 3d-transition metals
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Shaping distinct magnetic interactions in molecular compounds
2011, Journal of Magnetism and Magnetic MaterialsCitation Excerpt :Thus, the oxalates, located between metal ions, are bonded by one oxygen to metals, while at the extremity of the molecules, the metals are sharing two oxygen ions with the two OH neighbor groups. The most clear result is that all these compounds (except Fe2Co–a, see detailed discussion in [8]) have long range ordering to an essentially anti- ferromagnetic state with TN ranging between 10 K (FeFeCu-h) and 36.8 K (Fe2Co-h). Therefore, the inter-cluster interaction is quite effective in coupling their magnetic moments.
Magnetostructural correlations in the tetranuclear series of { Fe3 LnO2 } butterfly core clusters: Magnetic and Mössbauer spectroscopic study
2009, Physical Review B - Condensed Matter and Materials Physics
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