A Last Interglacial record of environmental changes from the Sulmona Basin (central Italy)
Introduction
The climate of the Last Interglacial (LIG), roughly corresponding to marine isotope stage (MIS) 5e and the Eemian interglacial in the European pollen stratigraphy (Govin et al., 2015 and references therein), has many features in common with model projections of future climate, because during this period much of the Earth experienced a climate warmer than present (e.g. Kukla et al., 2002). Although orbital parameters for MIS5e are quite different from that of the Holocene (e.g. Berger and Loutre, 1991), the LIG is a potential analog for projected future global warming and is thus an interesting study case for evaluating the climate and environmental responses during periods characterized by an excess of warmth. From this perspective, of particular interest are intra-interglacial millennial-scale climate changes. Evidence of abrupt climatic variations are well documented in several LIG records from North Atlantic marine sediments and Greenland ice (e.g. Oppo et al., 2001, Oppo et al., 2006, Galaasen et al., 2014, Pol et al., 2014) and some seem to have propagated into the Mediterranean basin (Sáñchez-Goñi et al., 1999, Martrat et al., 2004, Martrat et al., 2014, Sprovieri et al., 2006, Kandiano et al., 2014). Potential expressions of this oceanic driven instability have also been recognized in central Europe (e.g. Sirocko et al., 2005, Seelos and Sirocko, 2007, Seelos et al., 2009), as well as in the Mediterranean region (e.g. Tzedakis et al., 2003, Brauer et al., 2007, Drysdale et al., 2007, Couchoud et al., 2009, Milner et al., 2013, Milner et al., 2016, Regattieri et al., 2014a, Regattieri et al., 2016a, Vogel et al., 2010, Lézine et al., 2010, Zanchetta et al., 2016a). However, the effects of such changes on climate and ecosystems of the European continent are still poorly known and understood (Galaasen et al., 2014, Govin et al., 2015). Identification, correlation and evaluation of the climatic expressions of LIG millennial-scale variability outside the North Atlantic region remain unclear or largely based on postulated temporal phase relations. Addressing these issues requires the compilation of regionally representative, high-resolution and independently dated paleoclimatic records. Lacustrine successions deposited in tectonic basins of the Apennines are capable of fulfilling these requirements (Giaccio et al., 2015a, Giaccio et al., 2015b, Regattieri et al., 2015, Regattieri et al., 2016b, Russo-Ermolli et al., 2010) due to the high sensitivity of the local sediment properties, and particularly of the oxygen stable isotope composition of authigenic carbonates (δ18O), to hydrological and environmental changes. Moreover, these archives offer the possibility to develop independent age models based on the 40Ar/39Ar geochronometer, that can be directly or indirectly applied to the volcanic ash layers (tephra). These tephra layers, deriving from the intense activity of Quaternary peri-Tyrrhenian explosive volcanism, are systematically found in the lacustrine sediments of the Apennine intermountain basins (e.g. Giaccio et al., 2012, Petrosino et al., 2014, Giaccio et al., 2017).
Of the central Italian continental basins, Sulmona has already been recognized as a promising archive. The sedimentary record is underpinned by a robust tephrochronological framework (Giaccio et al., 2012, Giaccio et al., 2013a, Giaccio et al., 2013b), and provides important insights into climate and environmental evolution of the central Mediterranean and the linkages with extra-regional climate variability (Giaccio et al., 2015a, Regattieri et al., 2015, Regattieri et al., 2016b). In particular, the stable isotope profiles (δ18O and δ13C), CaCO3 content and tephrostratigraphy of the Popoli section (POP hereafter), documenting Early Last Glacial climate fluctuations (from ca. 115 to ca. 90 ka), highlight strong Mediterranean–North Atlantic climate teleconnections as well as the influence of low-latitude circulation patterns (Regattieri et al., 2015). In order to explore the environmental-hydrological changes over the entire early-to-middle MIS 5 (MIS 5e to MIS 5c, ca. 129–92 ka), and in particular the intra-LIG millennial scale variability, in this study we extended through a multiproxy approach (δ18O and δ13C analysis, CaCO3 content, biogenic silica content, XRF major and minor element composition, XRD-based bulk mineralogy and 40Ar/39Ar geochronology) the investigation of the POP section back to ca.129 ka. The results provide a longer and richer multi-proxy record, which allows a detailed reconstruction of local environmental change and give insights on potential relations with the extra-regional millennial-scale variability during the full LIG and at the LIG/Last Glacial transition.
Section snippets
Geological and stratigraphic setting
An up-dating stratigraphic framework of the Sulmona Basin (Fig. 1) is provided in Giaccio et al. (2009 with amendments in Giaccio et al., 2013a; 2012), Galli et al. (2015) and Regattieri et al., 2015, Regattieri et al., 2016b, to which the reader is referred for integrating the information summarized here. The Sulmona Basin (Fig. 1) is a block-faulted intermontane depression which accumulated lacustrine sediments discontinuously during the Quaternary (e.g. Cavinato et al., 1994, Cavinato and
Stratigraphy, sampling and stable isotope analyses
In the current study we present new results from a ~ 13.1 m-thick lacustrine interval recovered in the upper part of the ~ 60 m borehole described by Regattieri et al. (2015), which extends to ~ 40 m of the outcrop depth of the previous investigation (Fig. 1). At this depth (corresponding to ~ 23 m in core, Fig. 1), the lacustrine succession is interrupted by a hydromorphic paleosol with an upper Histic horizon, which marks the lowermost horizon investigated here. Below this peodogenic horizon (~ 1 m
40Ar/39Ar dating and chronology
Full analytical details for the 13 individual crystals analyses are given in Supplementary Table S1. Age-probability density spectra with individual single crystal age are presented Fig. 3. Among the 13 crystals analysed, ten yielded a similar age. These juvenile crystals allowed calculation of a weighted mean age of 109.5 ± 0.9 ka (2σ analytical uncertainty, P = 0.94).
The age model provided in Fig. 3 is based on the tephra layers discussed previously by Giaccio et al. (2012) and Regattieri et al.
Conclusions
In this work we have presented a multiproxy record (δ13C, δ18O, elemental composition, and low-resolution biogenic silica and mineralogy) obtained from lacustrine sediments of the Sulmona Basin (central Italy). It is anchored to an independent time-scale based on tephrochronology, here improved by a new direct 40Ar/39Ar age (109.5 ± 0.9 ka, 2σ analytical uncertainty) for the widespread X-6 Mediterranean marker. Specifically, six tephra layers account for a relatively constant history of the
Acknowledgments
This work was funded by the Australian Research Council Discovery Project DP160102969and by the University of Pisa through the project P.R.A. 2016 “Ruolo di zone di taglio nella costruzione degli orogeni: case histories da catene orogenetiche”. ER is supported by project SFB806 “Our way to Europe”. G. Zanchetta is thanked for discussion and comments to an early version of the manuscript. L. Folco is thanked for access to the HHXRF units, funded by the Italian “Ministero degli Affari Esteri e
References (135)
- et al.
Stable isotope (2H, 18O and 87Sr/86Sr) and hydrochemistry monitoring for ground water hydrodynamics analyses in a karst aquifer (Gran Sasso, Central Italy)
Appl. Geochem.
(2005) - et al.
Hydrological conditions in the western Mediterranean basin during the deposition of Sapropel 6 (ca. 175 kyr)
Earth Planet. Sci. Lett.
(2002) - et al.
Timing and hydrological conditions of Sapropel events in the eastern Mediterranean, as evident from speleothems, Soreq Cave, Israel
Chem. Geol.
(2000) - et al.
Sea–land oxygen isotopic relationships from planktonic foraminifera and speleothems in the Eastern Mediterranean region and their implication for paleorainfall during interglacial intervals
Geochim. Cosmochim. Acta
(2003) - et al.
Insolation values for the climate of the last 10 million years
Quat. Sci. Rev.
(1991) Methods and code for ‘classical’ age-modelling of radiocarbon sequences
Quat. Geochronol.
(2010)- et al.
Tephrochronology of core PRAD 1–2 in the Adriatic Sea: insights into Italian explosive volcanism for the period 200–80 ka
Quat. Sci. Rev.
(2015) The trace metal content of recent organic carbon-rich sediments: implications for Cretaceous black shale formation
Palaeogeogr. Palaeoclimatol. Palaeoecol.
(2006)- et al.
Evidence of enhanced Mediterranean thermohaline circulation during the rapid climatic coolings
Earth Planet. Sci. Lett.
(2000) - et al.
Millennial-scale variability during the Last Interglacial recorded in a speleothem from south-western France
Quat. Sci. Rev.
(2009)