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Subatmospheric Vapor Pressure Curves for Propionic Acid, Butyric Acid, Isobutyric Acid, Valeric Acid, Isovaleric Acid, Hexanoic Acid, and Heptanoic Acid

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Thermodynamics Research Unit, School of Chemical Engineering, University of Natal, Durban 4041, South Africa
Cite this: J. Chem. Eng. Data 2004, 49, 5, 1189–1192
Publication Date (Web):August 11, 2004
https://doi.org/10.1021/je034180e
Copyright © 2004 American Chemical Society

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    Abstract

    Vapor pressure data were measured for the following carboxylic acids:  propionic, butyric, isobutyric, valeric, isovaleric, hexanoic, and heptanoic acids. The pressure ranged between ∼5 kPa and atmospheric pressure (at sea level), and the corresponding temperatures were between 85 and 180 °C, depending on the acid being measured. The data were regressed using both the Antoine and Wagner equations, and the parameters obtained for each equation are presented. The experimental data were also compared to literature data, and the results are discussed.

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     Corresponding author. E-mail:  [email protected].

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