Abstract
Nafion® can be used as a solid polymer electrolyte in a PEM fuel cell. Direct platinization of the membrane was realized by chemical reduction of a platinum compound. The platinization procedure was modified to enhance the roughness factor and thus to improve the electrocatalytic activity towards ethanol electrooxidation. The Pt–PEM electrodes were characterized by TEM, atomic absorption analysis, cyclic voltammetry and their polarization curves for ethanol electrooxidation.
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R. A. Rightmire, R. L. Rowland, D. L. Boos and D. L. Beals, J. Electrochem. Soc. 111 (1964) 242.
J. Wang, S. Wasmus and R. Savinell, ibid. 142 (1995) 4218.
W. T. Grubb, J. Electroanal. Chem. 106 (1959) 275.
K. Kordesch and G. Simader in ‘Fuel Cells and their Applications’, VCH, Weinheim (1996), p. 151.
G. C. Scherer, T. Momose and K. Tomiie, J. Electrochem. Soc. 135 (1988) 3071.
H. Nakajima and H. Kita, Electrochim. Acta 33 (1988) 521.
P. Millet, F. Andolfatto and R. Durand, J. Appl. Electrochem. 25 (1995) 233.
R. Mosdale and S. Srinivasan, Electrochim. Acta 40 (1995) 413.
R. Liu, W. H. Her and P. S. Fedkiw, J Electrochem. Soc. 139 (1992) 15.
P. Millet, M. Pineri and R. Durand, J Appl. Electrochem. 19 (1989) 162.
P. Millet, F. Andolfatto and R. Durand, ibid. 25 (1995) 227.
P. S. Fedkiw and W. H. Her, J. Electrochem. Soc. 136 (1989) 899.
G. E. P Box and N. R. Draper, ‘Empirical Model Building and Response Surfaces’, J. Wiley & Sons, New York (1987); G.E.P Box, W. G. Hunter and J. S. Hunter ‘statistics for Experimenters’, J. Wiley & Sons, New York (1978).
E. A. Ticianelli, J. G. Beery and S. Srinivasan, J. Appl. Electrochem. 21 (1991) 597.
H. Takenaka, E. Torikai, Y. Kawami and N. Wakabayashi, Int J. Hydrogen. Energy 7 (1982) 397.
B. Beden, M. C. Morin, F. Hahn and C. Lamy, J. Electroanal. Chem. 229 (1987) 353.
B. Beden, J. M. Léger and C. Lamy in ‘Modern Aspect of Electrochemistry’, Vol. 22 (edited by J. O'M. Bockris, B. E. Conway and R. E. White), Plenum Press, New York (1992), ch. 2, p. 97.
B. Beden, F. Hahn, C. Lamy, J. M. Léger, N. R. de Tacconi, R. O. Lezna and A. J. Arvia, J. Electroanal. Chem. 261 (1989) 401.
A. Gamez, D. Richard., P. Gallezot, F. Gloaguen, R. Faure and R. Durand, Electrochim. Acta 41 (1996) 307.
K. Shimazu, K. Uosaki, H. Kita and Y. Nodasaka, J. Electroanal. Chem. 256 (1988) 481.
B. Beden, C. Lamy, N. R. de Tacconi and A. J. Arvia Electrochim. Acta 35 (1990) 691.
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Delime, F., Le´Ger, J.M. & Lamy, C. Optimization of platinum dispersion in Pt–PEM electrodes: application to the electrooxidation of ethanol. Journal of Applied Electrochemistry 28, 27–35 (1998). https://doi.org/10.1023/A:1003289516328
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DOI: https://doi.org/10.1023/A:1003289516328