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Optimization of platinum dispersion in Pt–PEM electrodes: application to the electrooxidation of ethanol

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Abstract

Nafion® can be used as a solid polymer electrolyte in a PEM fuel cell. Direct platinization of the membrane was realized by chemical reduction of a platinum compound. The platinization procedure was modified to enhance the roughness factor and thus to improve the electrocatalytic activity towards ethanol electrooxidation. The Pt–PEM electrodes were characterized by TEM, atomic absorption analysis, cyclic voltammetry and their polarization curves for ethanol electrooxidation.

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References

  1. R. A. Rightmire, R. L. Rowland, D. L. Boos and D. L. Beals, J. Electrochem. Soc. 111 (1964) 242.

    Article  CAS  Google Scholar 

  2. J. Wang, S. Wasmus and R. Savinell, ibid. 142 (1995) 4218.

    Article  CAS  Google Scholar 

  3. W. T. Grubb, J. Electroanal. Chem. 106 (1959) 275.

    CAS  Google Scholar 

  4. K. Kordesch and G. Simader in ‘Fuel Cells and their Applications’, VCH, Weinheim (1996), p. 151.

    Google Scholar 

  5. G. C. Scherer, T. Momose and K. Tomiie, J. Electrochem. Soc. 135 (1988) 3071.

    Article  CAS  Google Scholar 

  6. H. Nakajima and H. Kita, Electrochim. Acta 33 (1988) 521.

    Article  CAS  Google Scholar 

  7. P. Millet, F. Andolfatto and R. Durand, J. Appl. Electrochem. 25 (1995) 233.

    CAS  Google Scholar 

  8. R. Mosdale and S. Srinivasan, Electrochim. Acta 40 (1995) 413.

    Article  CAS  Google Scholar 

  9. R. Liu, W. H. Her and P. S. Fedkiw, J Electrochem. Soc. 139 (1992) 15.

    Article  CAS  Google Scholar 

  10. P. Millet, M. Pineri and R. Durand, J Appl. Electrochem. 19 (1989) 162.

    Article  CAS  Google Scholar 

  11. P. Millet, F. Andolfatto and R. Durand, ibid. 25 (1995) 227.

    CAS  Google Scholar 

  12. P. S. Fedkiw and W. H. Her, J. Electrochem. Soc. 136 (1989) 899.

    Article  CAS  Google Scholar 

  13. G. E. P Box and N. R. Draper, ‘Empirical Model Building and Response Surfaces’, J. Wiley & Sons, New York (1987); G.E.P Box, W. G. Hunter and J. S. Hunter ‘statistics for Experimenters’, J. Wiley & Sons, New York (1978).

    Google Scholar 

  14. E. A. Ticianelli, J. G. Beery and S. Srinivasan, J. Appl. Electrochem. 21 (1991) 597.

    Article  CAS  Google Scholar 

  15. H. Takenaka, E. Torikai, Y. Kawami and N. Wakabayashi, Int J. Hydrogen. Energy 7 (1982) 397.

    Article  CAS  Google Scholar 

  16. B. Beden, M. C. Morin, F. Hahn and C. Lamy, J. Electroanal. Chem. 229 (1987) 353.

    Article  CAS  Google Scholar 

  17. B. Beden, J. M. Léger and C. Lamy in ‘Modern Aspect of Electrochemistry’, Vol. 22 (edited by J. O'M. Bockris, B. E. Conway and R. E. White), Plenum Press, New York (1992), ch. 2, p. 97.

    Google Scholar 

  18. B. Beden, F. Hahn, C. Lamy, J. M. Léger, N. R. de Tacconi, R. O. Lezna and A. J. Arvia, J. Electroanal. Chem. 261 (1989) 401.

    Article  CAS  Google Scholar 

  19. A. Gamez, D. Richard., P. Gallezot, F. Gloaguen, R. Faure and R. Durand, Electrochim. Acta 41 (1996) 307.

    Article  CAS  Google Scholar 

  20. K. Shimazu, K. Uosaki, H. Kita and Y. Nodasaka, J. Electroanal. Chem. 256 (1988) 481.

    Article  CAS  Google Scholar 

  21. B. Beden, C. Lamy, N. R. de Tacconi and A. J. Arvia Electrochim. Acta 35 (1990) 691.

    Article  CAS  Google Scholar 

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Delime, F., Le´Ger, J.M. & Lamy, C. Optimization of platinum dispersion in Pt–PEM electrodes: application to the electrooxidation of ethanol. Journal of Applied Electrochemistry 28, 27–35 (1998). https://doi.org/10.1023/A:1003289516328

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  • DOI: https://doi.org/10.1023/A:1003289516328

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