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A new method for electrochemical screening basedon the rotating ring disc electrode and its applicationto oxygen reduction catalysts

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Abstract

A new method for electrochemical characterization of composite electrode materials is reported. A paste of the catalytic material in Nafion® is coated on a rotating ring disc electrode (RRDE) to partially simulate the working environment of a proton exchange membrane (PEM)/electrode composite as used in, for example, water electrolysis or PEM fuel cell operation. This allows direct comparison of a wide range of candidate electrocatalysts in a reproducible manner. Problems specific to these volumic electrodes are accommodated satisfactorily by rational modification of the standard expressions used in RRDE analysis. The value of the method is illustrated in studies of various cobalt complexes which show promise in dioxygen reduction; namely, cobalt tetramethoxyphenylporphyrin (CoTMPP), cobalt phthalocyanine (CoPC), and cobalt cyclam (CoCy), supported on a range of particulate carbons BP2000, Printex XE 2 and Vulcan XC-72. Typical electrochemical parameters have been measured or estimated, including half-wave potentials (E1/2), Tafel slopes (b), ‘activation currents’ (Ia) and the average number of electrons transferred (n). The nature of the complex itself and the carbon support have a strong influence on electrode behaviour. Ligands with more aromatic character give better performance. Dramatic improvements in performance result from heat pretreatment, which is tentatively attributed to the formation of dimeric cobalt species via thermally-induced aggregation. In terms of the four electron reduction (to water), the best result was obtained for CoTMPP on Printex XE2 and rationalized on the basis of popular current views on the mechanism and catalyst functionality. CoPC on BP2000 is unusual in showing a strong change in n with reduction potential. Product selectivity ranges between mainly hydrogen peroxide (n=2) and water (n=4) with increasing overpotential.

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References

  1. H. Tannenberger, La Recherche 3 (1970) 231.

    Google Scholar 

  2. R. Mosdale, Thesis, Institut National Polytechnique de Grenoble (1992).

  3. A. Parthasarathy, C. R. Martin and S. Srinivasan, J. Electrochem. Soc. 138 (1991) 916.

    Article  CAS  Google Scholar 

  4. A. J. Appleby and B. S. Baker, ibid. 125 (1978) 404.

  5. M. A. Enayetullah, E. J. M. O'Sullivan and E. B. Yeager, J. Appl. Electrochem. 18 (1988) 763.

    Article  CAS  Google Scholar 

  6. F. A. Uribe, T. E. Springer and S. Gottesfeld, J. Electrochem. Soc. 139 (1992) 765.

    Article  CAS  Google Scholar 

  7. K. Wiesener, Electrochim. Acta 31 (1986) 1073.

    Article  CAS  Google Scholar 

  8. A. L. Bouwkamp-Wijnoltz, W. Visscher and J. A. R. Van Veen, ibid. 39 (1994) 1641.

    Article  CAS  Google Scholar 

  9. A. Van Der Putten, A. Elzing and E. Barendrecht, J. Electroanal. Chem. 221 (1987) 95.

    Article  CAS  Google Scholar 

  10. C-L. Ni, I. Abdalmuhdi, C. K. Chang and F. C. Anson, J. Phys. Chem. 91 (1987) 1158.

    Article  CAS  Google Scholar 

  11. J. Zagal, M. Paez, A. A. Tanaka, J. R. Dos Santos and C.A. Linkous, J. Electroanal Chem. 339 (1992) 13.

    Article  CAS  Google Scholar 

  12. L. Y. Johansson and R. Larsson, J. Mol. Cataly. 38 (1986) 61.

    Article  CAS  Google Scholar 

  13. O. Ikeda, T. Kojima and H. Tamura, Bull. Chem. Soc. Jpn. 59 (1986) 3335.

    Article  CAS  Google Scholar 

  14. M. Ladouceur, G. Lalande, D. Guay, J. P. Dodelet, L. Dignard-Bailey, M. L. Trudeau and R. Schulz, J. Electrochem. Soc. 140 (1993) 1974.

    Article  CAS  Google Scholar 

  15. G. Tamizhmani, J. P. Dodelet, D. Guay, G. Lalande and G. A. Capuano, J. Electrochem. Soc. 141 (1994) 41.

    Article  CAS  Google Scholar 

  16. N. Phougat, P. Vasudevan, Santosh and A. K. Shukla, J. Power Sources 46 (1993) 61.

    Article  CAS  Google Scholar 

  17. J. Zagal, P. Bindra and E. B. Yeager, J. Electrochem. Soc. 127 (1980) 1506.

    Article  CAS  Google Scholar 

  18. I. Iliev, S. Gamburzev and A. Kaisheva, J. Power Sources 17 (1986) 345.

    Article  CAS  Google Scholar 

  19. J. A. R. Van Veen, J. F. Van Baar and K. J. Kroese, J. Chem. Soc. Faraday Trans. 1 77 (1981) 2827.

    Article  CAS  Google Scholar 

  20. T-C. Sheng, B. Rebenstorf, A. Widelöv and R. Larsson, J. Chem. Soc. Faraday Trans. 88 (1992) 477.

    Article  CAS  Google Scholar 

  21. A. Widelöv, Electrochim. Acta 38 (1993) 2493.

    Article  Google Scholar 

  22. A. Biloul, O. Contamin, G. Scarbeck, M. Savy, D. Van Den Ham, J. Riga and J. J. Verbist, J. Electroanal. Chem. 335 (1992) 163.

    Article  CAS  Google Scholar 

  23. A. Biloul, O. Contamin, G. Scarbeck, M. Savy, B. Palys, J. Riga and J. J. Verbist, J. Electroanal. Chem. 365 (1994) 239.

    Article  CAS  Google Scholar 

  24. A. Biloul, F. Coowar, O. Contamin, G. Scarbeck, M. Savy, D. Van Den Ham, J. Riga and J. J. Verbist, ibid. 350 (1993) 189.

    Article  CAS  Google Scholar 

  25. G. Tamizhmani, J. P. Dodelet, D. Guay, G. Lalande and G. A. Capuano, J. Electrochem. Soc. 141, (1994) 41.

    Article  CAS  Google Scholar 

  26. B. Bittins-Cattaneo, S. Wasmus, B. Lopez-Mishima and W. Vielstich, J. Appl. Electrochem. 23 (1993) 625.

    Article  CAS  Google Scholar 

  27. J. A. R. Van Veen, Electrochim. Acta 27 (1982) 1403.

    Article  CAS  Google Scholar 

  28. G. Lalande, R. Côté, G. Tamizhmani, D. Guay, J. P. Dodelet, L. Dignard-Bailey, L. T. Weng and P. Bertrand, ibid. 40 (1995) 2635.

    Article  CAS  Google Scholar 

  29. B. Bosnich, C. K. Poon and M. L. Tobe, Inorg. Chem. 4 (1965) 1102.

    Article  CAS  Google Scholar 

  30. S. Matsupka, K. Yamamoto, T. Ogata, M. Kusaba, N. Nakashima, E. Fujita and S. Yanagida, J. Am. Chem. Soc. 115 (1993) 601.

    Article  Google Scholar 

  31. W. J. Albery and M. L. Hitchman, ‘Ring-disc Electrodes’, Oxford University Press (1971).

  32. J. P. Collman, M. Marrocco and P. Denisevich, J. Electroanal. Chem. 101 (1979) 117.

    Article  CAS  Google Scholar 

  33. J. P. Collman, P. Denisevich, Y. Konai, M. Marrocco, C. Koval and F. C. Anson, J. Am. Chem. Soc. 102 (1980) 6027.

    Article  CAS  Google Scholar 

  34. Y. Le Mest, M. L'Her, J. Courtot-Coupez, J. P. Collman, E. R. Evitt and C. S. Bencosme, J. Chem. Soc., Chem. Com. (1983) 1286.

  35. R. R. Durand, C. S. Bencosme, J. P. Collman and F. C. Anson, J. Am. Chem. Soc. 105 (1983) 2710.

    Article  CAS  Google Scholar 

  36. Y. Le Mest, M. L'Her, J. P. Collman, K. Kim, N. H. Hendricks and S. Helm, J. Electroanal. Chem. 234 (1987) 277.

    Article  CAS  Google Scholar 

  37. E. Ngameni, Y. Le Mest, M. L'Her, J. P. Collman, N. H. Hendricks and K. Kim, ibid. 220 (1987) 247.

    Article  CAS  Google Scholar 

  38. J. P. Collman, N. H. Hendricks, K. Kim and C. S. Bencosme, J. Chem. Soc., Chem. Com. (1987) 1537.

  39. H.-Y. Liu, I. Abdalmuhdi, C. K. Chang and F. C. Anson, J. Phys. Chem. 89 (1985) 675.

    Google Scholar 

  40. C-L. Ni, I. Abdalmuhdi, C. K. Chang and F. C. Anson, ibid. 91 (1987) 1158.

    Article  CAS  Google Scholar 

  41. A. Van Der Putten, A. Elzing, W. Visscher and E. Barendrecht, J. Electroanal. Chem. 205 (1986) 233.

    Article  CAS  Google Scholar 

  42. T. Sawaguchi, T. Itabashi, T. Matsue and I. Uchida, ibid. 279 (1990) 219.

    Article  CAS  Google Scholar 

  43. V. S. Bagotzky, M. R. Tarasevich, K. A. Radyushkina, O. A. Levina and S. I. Andrusyova, J. Power Sources 2 (1977/78) 233.

    Article  Google Scholar 

  44. S. Srinivasan, O. A. Velev, A. Parthasarathy, D. J. Manko and A. J. Appleby, ibid. 36 (1991) 299.

    Article  CAS  Google Scholar 

  45. Y. Le Mest, M. L'Her, J. Courtot-Coupez, J. P. Collman, E. R. Evitt and C. S. Bencosme, J. Electroanal. Chem. 184 (1985) 331.

    Article  CAS  Google Scholar 

  46. J. P. Collman, N. H. Hendricks, C. R. Leidner, E. Ngameni and M. L'Her, Inorg. Chem. 27 (1988) 387.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. De´partement de la Recherche Fondamentale sur la Matiere Condense´e, Commissariat a´ l'Energie Atomique, SI3M/PCM 17 rue des Martyrs, 38054, Grenoble Cedex 9, France

    E. Claude, T. Addou, J.-M. Latour & P. Aldebert

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  1. E. Claude
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  2. T. Addou
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  3. J.-M. Latour
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  4. P. Aldebert
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Claude, E., Addou, T., Latour, JM. et al. A new method for electrochemical screening basedon the rotating ring disc electrode and its applicationto oxygen reduction catalysts. Journal of Applied Electrochemistry 28, 57–64 (1998). https://doi.org/10.1023/A:1003297718146

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