Abstract
The chemical partitioning of lead and zinc is described in contaminated soils and underlying strata at historical lead smelting sites. Sections of soil-rock cores from eight sites of age 200 to c.1900 yr were analysed using a sequential extraction procedure. Of the total amount of lead and zinc present in soils, only a small proportion is in a readily mobile form. However, this proportion increases significantly as the pH falls below 5 and for lead reaches 37% in soils at Bole A. A high proportion of lead in soils appears to be associated with the carbonate and specifically adsorbed phase. It is suggested that this is partly due to the formation of cerussite (PbCO3) in soils contaminated with calcareous slag wastes. Lead present in the residual phase in contaminated soils may be related to the presence of the element in silicate slag particles. Rapid migration of lead to a depth of 5.6 m in sandstone at Bole A was related to its high solubility in the acidic soils and rock at this site. Comparable migration at Bole C proceeds by a different mechanism, possibly with lead in association with Fe-Mn oxides and slag particles. In clay infill in fractured sandstone at Bole A, anthropogenic lead present at a depth of 4.4 m was extracted predominantly in the fraction representing Fe-Mn oxides.
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References
Brookins, D. G.: 1988, Eh-pH Diagrams for Geochemistry, Springer Verlag, New York.
Clevenger, T. E.: 1990, Water, Air, and Soil Pollut. 50, 241.
Dorr, H. and Munnich, K. O.: 1991, Water, Air and Soil Pollut. 57-58, 809.
Dumontet, S., Levesque, M and Mathur, S. P.: 1990, Water, Air and Soil Pollut. 49, 329.
Forstner, U.: 1985, ‘Chemical Forms and Reactivities of Metals in Sediment’, in R. Leschber, R.D. Davis and P. L'Hermite (eds.), Chemical Methods for Assessing Bio-Available Metals in Sludges and Soils. Elsevier, London, pp 1-31.
Gee, C., Ramsey, M. H., Maskall, J. E. and Thornton, I.: 1997, J. Geochem. Expl. 58, 249.
Gibb, J. P. and Cartwright, K.: 1982, Retention of Zinc, Cadmium, Copper and Lead by Geologic Materials, Co-operative Groundwater Report 9, Illinois State Water Survey, Illinois State Geological Survey, pp. 113.
Gibson, M. J. and Farmer, J. G.: 1984, Sci. Total Environ. 33, 49.
Gibson, M. J. and Farmer, J. G.: 1986, Env. Poll. Ser. B 11, 117.
Harrison, R. M., Laxen, D. P. H., and Wilson, S. J.: 1981, Env. Sci. Tech. 15, 1378.
Hickey, M. G. and Kittrick, J. A.: 1984, J. Environ. Qual. 13 372.
Iyengar, S. S., Martens, D. C. and Miller, W. P.: 1981, Soil. Sci. Soc. Am. J. 45, 735.
Jouanneau, J. M., Latouche, C. and Pautrizel, F.: 1983, Environ. Technol. Lett. 4, 509.
Kheboian, C. and Bauer, C.: 1987, Anal. Chem. 59, 1417.
Kim, N. D. and Fergusson, J. E.: 1991, Sci. Total Environ. 105, 191.
Kobuty-Amacher, J., Gambrell, R. P. and Amacher, M.C.: 1992, ‘The Distribution and Environmental Chemistry of Lead in Soil at an Abandoned Battery Reclamation Site’, in I.K. Iskander and H.M. Selim (eds.), Engineering Aspects of Metal-Waste Management, Lewis, Michigan, pp. 1–24.
Korte, N. E., Skopp, J., Fuller, W. H., Niebla, E. E. and Alesii, A.: 1976, Soil Sci. 122, 350.
Kuo, S., Heilman, P. E., and Baker, A. S.: 1983, Soil Sci. 135, 101.
Li, X.: 1993, ‘The Study of Multielement Associations in the Soil-Plant System in Some Old Metalliferous Mining Areas, England’, PhD Thesis, University of London.
Li, X., Coles, B., Ramsey, M. H. and Thornton, I.: 1995, Chem Geol. 124, 109.
Martin, J. M., Nirel, P. and Thomas, A. J.: 1987, Mar. Chem. 22, 313.
Maskall, J. E., Whitehead, K. and Thornton, I.: 1995, Env. Geochem. 17, 127.
Maskall, J. E., Whitehead, K., Gee, C., and Thornton, I.: 1996, Appl. Geochem. 11, 43.
Newman, J. R. and Ross, C. A. M.: 1987, Mineralogical and Geochemical Controls on Heavy Metal Pollution in Monolith Lysimeters, Report FLPU 85-5, British Geological Survey, Keyworth, pp. 128.
Tessier, A., Campbell, P. G. C. and Bisson, M.: 1979, Anal. Chem. 51, 844.
Thompson, M. and Walsh, J. N.: 1983, A Handbook of Inductively Coupled Plasma Atomic Emission Spectrometry, Blackie, Glasgow.
Quevauvillier, Ph., van der Sloot, H. A., Ure, A., Munbau, H., Gomez, A. and Rauret, G.: 1996, Sci. Total Environ. 178, 133.
Valin, R. V. and Morse, J. M.: 1982, Mar. Chem. 11, 535.
Whitehead, K., Ramsey, M. H., Maskall, J. E., Thornton, I. and Bacon, J. R.: 1997, Appl. Geochem. 12, 75.
Yanful, E. K., Quigley, R. M. and Nesbitt, H. W.: 1988, Appl. Geochem. 3, 623.
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Maskall, J.E., Thornton, I. Chemical Partitioning of Heavy Metals in Soils, Clays and Rocks at Historical Lead Smelting Sites. Water, Air, & Soil Pollution 108, 391–409 (1998). https://doi.org/10.1023/A:1005029310495
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DOI: https://doi.org/10.1023/A:1005029310495