Abstract
Ambient atmospheric aerosols and savanna fireparticulate emission samples from southern Africa werecharacterised in terms of particle classes and theirnumber abundance by electron probe X-ray microanalysis(EPXMA). About ten particle classes were identifiedfor each sample. The major classes werealuminosilicates and sea salts for ambient coarse(2–10 μm equivalent aerodynamic diameter (EAD))samples, and K-S and S-only particles for ambient fine(<2 μm EAD) samples. The K-S particles are oneof the major products of biomass burning. The EPXMAresults were found to be consistent with the resultsfrom bulk analyses on a sample by sample basis. Forsavanna fire fine samples, quantitative EPXMA revealedthat many particles had a composition of simple saltssuch as KCl. Some particles had a deviatingcomposition in the sense that more ionic species wereinvolved in sustaining the balance between cations andanions, and they were composite or mixed salts.Because of extensive processing during the atmospherictransport, the composition of the K-S particles in theambient samples was different from K2SO4,and such particles were enriched with S. The finepyrogenic KCl particles and the fine sea-saltparticles were much depleted in chlorine.
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Allen, A. G. and Miguel, A. H., 1995: Biomass burning in the Amazon: Characterization of the ionic component of aerosols generated from flaming and smouldering rain forest and savanna, Environ. Sci. Technol. 29, 486–493.
Anderson, J. R., Buseck, P. R., Patterson, T. L., and Arimoto, R., 1996: Characterization of the Bermuda tropospheric aerosol by combined individual particle and bulk-aerosol analysis, Atmos. Environ. 30, 319–338.
Andreae, M. O., 1983: Soot carbon and excess fine potassium: Long-range transport of combustion derived aerosols, Science 220, 1148–1151.
Andreae, M. O., Charlson, R. J., Bruynseels, F., Storms, H., Van Grieken, R., and Maenhaut, W., 1986: Internal mixture of sea salt, silicates, and excess sulphate in marine aerosols, Science 232, 1620–1623.
Andreae, M. O., 1993a: Global distribution of fires seen from space, Eos Trans. AGU 74, 129.
Andreae, M. O., 1993b: personal communication.
Andreae, M. O., Fishman, J., and Lindesay, J., 1996: The southern tropical Atlantic region experiment (STARE): Transport and atmospheric chemistry near the Equator-Atlantic (TRACE-A) and southern African fire-atmosphere research initiative (SAFARI): An introduction, J. Geophys. Res. 101, 23519–23520.
Artaxo, P., Rabello, M. L. C., Maenhaut, W., and Van Grieken, R., 1992: Trace elements and individual particle analysis of atmospheric aerosols from the Antarctic peninsula, Tellus 44B, 318–334.
Bondarenko, I., Van Malderen, H., Treiger, B., Van Espen, P., and Van Grieken, R. 1994: Hierarchical cluster analysis with stopping rules built on Akaike's information criterion for aerosol particle classification based on electron probe X-ray microanalysis, Chemom. Intell. Lab. Syst. 22, 87–95.
Bondarenko, I., Treiger, B., Van Grieken, R., and Van Espen P., 1996: IDAS: a Windows based software package for cluster analysis, Spectrochim. Acta B 51, 441–456.
Van Borm, W. A., Adams, F. C., and Maenhaut, W., 1989: Characterization of individual particles in the Antwerp aerosol, Atmos. Environ. 23, 1139–1151.
Cachier, H., Ducret, J., Brémond, M.-P., Yoboué, V., Lacaux, J.-P., Gaudichet, A., and Baudet, J., 1991: Biomass burning aerosols in a savannah region of the Ivory Coast, in J. S. Levine (ed.), Global Biomass Burning: Atmospheric, Climatic and Biospheric Implications, MIT Press, Cambridge, MA, pp. 174–180.
Cahoon, D. R., Jr, Stocks, B. J., Levine, J. S., Cofer, W. R., III, and O'Neill, K. P., 1992: Seasonal distribution of African savanna fires, Nature 359, 812–815.
Charlson, R. J. and Heintzenberg, J., (eds), 1995: Aerosol Forcing of Climate, Wiley, Chichester.
Van Espen, P., 1984: A program for the processing of analytical data (DPP), Anal. Chim. Acta 165, 31–49.
Van Espen, P. 1994: Quantitative microbeam analysis of particles, Mikrochim. Acta 114/115, 129–142.
Gaudichet, A., Echalar, F., Chatenet, B., Quisefit, J. P., Malingre, G., Cachier, H., Buat-Minard, P., Artaxo, P., and Maenhaut, W., 1995: Trace elements in tropical African savanna biomass burning aerosols, J. Atmos. Chem. 22, 19–39.
Graedel, T. E. and Keene, W. C., 1995: Tropospheric budget of reactive chlorine, Global Biogeochem. Cycles 9, 47–77.
Hoornaert, S., Van Malderen, H., and Van Grieken, R., 1996: Gypsum and other calcium-rich aerosol particles above the North Sea, Environ. Sci. Technol. 30, 1515–1520.
Jambers, W., De Bock, L., and Van Grieken, R., 1995: Recent advances in the analysis of individual environmental particles: a review, Analyst 120, 681–692.
Katrinak, K. A., Anderson, J. R., and Buseck, P. R., 1995: Individual particle types in the aerosol of Phoenix, Arizona, Environ. Sci. Technol. 29, 321–329.
Lacaux, J. P., Delmas, R., Jambert, C., and Kuhlbusch, T. A. J., 1996: NOx emissions from African savanna fires, J. Geophys. Res. 101, 23585–23595.
Levine, J. S., Cofer, W. R., III, Cahoon D. R., and Winstead, E. L., 1995: Biomass burning: A driver for global change, Environ. Sci. Technol. 29, 120A-125A.
Lindesay, J. A., Andreae, M. O., Goldammer, J. G., Harris, G., Annegarn, H. J., Garstang, M., Scholes, R. J., and Van Wilgen, B. W., 1996: International geosphere-biosphere programme/ international global atmospheric chemistry SAFARI-92 field experiment: Background and overview, J. Geophys. Res. 101, 23521–23530.
Maenhaut, W., François, F., and Cafmeyer, J., 1994: Regional and global atmospheric aerosol studies using the ‘Gent’ stacked filter unit and other aerosol collectors, with multi-elemental analysis of the samples by nuclear-related analytical techniques, in Applied Research on Air Pollution Using Nuclear-Related Analytical Techniques, Report NAHRES-19, IAEA, Vienna, pp. 249–263.
Maenhaut, W., Salma, I., Cafmeyer, J., Annegarn, H. J., and Andreae, M. O., 1996: Regional atmospheric aerosol composition and sources in the eastern Transvaal, South Africa, and impact of biomass burning, J. Geophys. Res. 101, 23631–23650.
Van Malderen, H., Van Grieken, R., Bufetov, N. V., and Koutzenogii, K. P., 1996a: Chemical characterization of individual aerosol particles in central Siberia, Environ. Sci. Technol. 30, 312–321.
Van Malderen, H., Hoornaert, S., and Van Grieken, R., 1996b: Identification of individual aerosol particles containing Cr, Pb, and Zn above the North Sea, Environ. Sci. Technol. 30, 489–498.
Martins, J. V., Artaxo, P., Hobbs, P. V., Liousse, C., Cachier, H., Kaufman, Y., and Plana-Fattori, A., 1996: Particle-size distributions, elemental compositions, and optical properties of smoke from biomass burning in the Pacific Northwest of the United States, in J. S. Levine (ed.), Biomass Burning and Global Change, MIT Press, Cambridge, MA, pp. 716–732.
McMurry, P. H., Litchy, M., Huang, P.-F., Cai, X., Turpin, B. J., Dick, W. D., and Hanson, A., 1996: Elemental composition and morphology of individual particles separated by size and hygroscopicity with the TDMA, Atmos. Environ. 30, 101–108.
Parungo, F., Kopcewicz, B., Nagamoto, C., Schnell, R., Sheridan, P., Zhu, C., and Harris, J., 1992: Aerosol particles in the Kuwait oil fire plumes: Their morphology, size distribution, chemical composition, transport, and potential effect on climate, J. Geophys. Res. 97, 15867–15882.
Posfai, M., Anderson, J. R., Buseck, P. R., and Sievering, H., 1995: Compositional variations of sea-salt-mode aerosol particles from the North Atlantic, J. Geophys. Res. 100, 23063–23074.
Raeymaekers, B., Demuynck, M., Dorriné, W., and Adams, F., 1988: Characterization of oil fly ash particles by electron probe microanalysis, Intern. J. Environ. Anal. Chem. 32, 291–312.
Shattuck, T. W., Germani, M. S., and Buseck, P. R., 1991: Multivariate statistics for large data sets: Applications to individual aerosol particles, Anal. Chem. 63, 2646–2656.
Sheridan, P. J., Schnell, R. C., Hofmann, D. J., Harris, J. M., and Deshler, T., 1992: Electron microscope studies of aerosol layers with likely Kuwait origins over Laramie, Wyoming during spring 1991, Geophys. Res. Lett. 19, 389–392.
Stocks, B. J., van Wilgen, B. W., Trollope, W. S. W., McRae, D. J., Mason, J. A., Weirich, F., and Potgieter, A. L. F., 1996: Fuels and fire behavior dynamics on large-scale savanna fires in Kruger National Park, South Africa, J. Geophys. Res. 101, 23541–23550.
Trollope, W. S. W., Trollope, L. A., Potgieter, A. L. F., and Zambatis, N., 1996: SAFARI-92, characterization of biomass and fire behavior in the small experimental burns in the Kruger National Park, J. Geophys. Res. 101, 23531–23539.
Weast, R. C., (ed.), 1982–1983: CRC Handbook of Chemistry and Physics, Edition 63, CRC Press, Boca Raton, FL.
Woods, D. C., Chuan R. L., Cofer W. R., III, and Levine, J. S., 1991: Aerosol characterization in smoke plumes from burning at a Florida wildlife refuge, in J. S. Levine (ed.), Global Biomass Burning: Atmospheric, Climatic and Biospheric Implications, MIT Press, Cambridge, MA, pp. 240–244.
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Liu, X., Van Espen, P., Adams, F. et al. Biomass Burning in Southern Africa: Individual Particle Characterization of Atmospheric Aerosols and Savanna Fire Samples. Journal of Atmospheric Chemistry 36, 135–155 (2000). https://doi.org/10.1023/A:1006387031927
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DOI: https://doi.org/10.1023/A:1006387031927