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Progress of enantio-differentiating hydrogenation of prochiral ketones over asymmetrically modified nickel catalysts and a newly proposed enantio-differentiation model

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Abstract

This article reviews the enantio-differentiating hydrogenation of various prochiral ketones over asymmetrically modified Ni catalysts. Development from the discovery to the state of the art of the modified Ni catalyst is surveyed. Understanding and interpretation of this catalyst is discussed and new enantio-differentiation models are proposed.

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Authors and Affiliations

  1. Faculty of Science, Toyama University, Gofuku, Toyama, 930–8555, Japan

    Tsutomu Osawa & Osamu Takayasu

  2. Faculty of Science and Technology, Ryukoku University, Seta, Otsu, 520–2194, Japan

    Tadao Harada

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  1. Tsutomu Osawa
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  2. Tadao Harada
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  3. Osamu Takayasu
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Osawa, T., Harada, T. & Takayasu, O. Progress of enantio-differentiating hydrogenation of prochiral ketones over asymmetrically modified nickel catalysts and a newly proposed enantio-differentiation model. Topics in Catalysis 13, 155–168 (2000). https://doi.org/10.1023/A:1009042602411

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