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Oxygen Diffusion in Single- and Poly-Crystalline Zinc Oxides

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Abstract

18O diffusion coefficients were measured in zinc oxide ceramics using a secondary ion mass spectrometer. The results are interpreted as indicating extrinsic behavior. The values of the lattice diffusion coefficients with higher valence dopants compared with zinc ions are greater than lower valence dopant such as lithium ions. Using the data at deeper depth, the grain boundary diffusivity of oxide ions was also evaluated. Although the lattice diffusion coefficients varied by two orders of magnitude, the products of grain boundary width and grain boundary diffusion coefficient were less sensitive to the type of dopants.

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Authors and Affiliations

  1. National Institute for Research in Inorganic Materials, 1-1 Namiki, Tsukuba-shi, Ibaraki, 305-0044, Japan

    Hajime Haneda, Isao Sakaguchi, Akio Watanabe, Takamasa Ishigaki & Junzo Tanaka

Authors
  1. Hajime Haneda
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  2. Isao Sakaguchi
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  3. Akio Watanabe
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  4. Takamasa Ishigaki
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  5. Junzo Tanaka
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Haneda, H., Sakaguchi, I., Watanabe, A. et al. Oxygen Diffusion in Single- and Poly-Crystalline Zinc Oxides. Journal of Electroceramics 4 (Suppl 1), 41–48 (1999). https://doi.org/10.1023/A:1009969600587

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  • DOI: https://doi.org/10.1023/A:1009969600587

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