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Kinetics and Mechanism of the Oxidative Regeneration of Carbonyl Compounds from Oximes by Pyridinium Fluorochromate

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Abstract

Oxidative deoximination of aldoximes and ketoximes by pyridium fluorochromate proceeds by nucleophilic attack of the chromate oxygen on the oxime carbon to give a cyclic intermediate in the rate-determining step.

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REFERENCES

  1. H. Firouzabadi, A. Sadarian: Synth. Commun., 13, 863 (1983); J. Drabowicz: Synthesis, 125 (1980); P.B. Hopkins, S. Kim, S. Yoo, K.P. Nambiar, J.R. Flack: J. Am. Chem. Soc., 101, 7131 (1979).

    Google Scholar 

  2. M.N. Bhattacharjee, M.K. Chaudhuri, H.S. Dasgupta, N. Roy, D.T. Kathing: Synthesis, 588 (1982).

  3. I.M. Baltrok, M.M. Sadegi, N. Mahmoodi, B. Kharamesh: Indian J. Chem., 36B, 438 (1997).

    Google Scholar 

  4. K.B. Sharpless, A.Y. Teranishi, J.E. Bäckvall: J. Am. Chem. Soc., 99, 3120 (1977).

    Google Scholar 

  5. W.A. Pavelich, R.W. Taft: J. Am. Chem. Soc., 79, 4935 (1957).

    Google Scholar 

  6. G. Maier, H.P. Reisenauer, M.D. Marco: Angew. Chem. Int. Ed., 38, 108 (1999).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, J.N.V. University, Jodhpur, 342005, India

    Abhinav Bhandari, Pallavi Mishra & Kalyan K. Banerji

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  1. Abhinav Bhandari
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  2. Pallavi Mishra
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  3. Kalyan K. Banerji
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Bhandari, A., Mishra, P. & Banerji, K.K. Kinetics and Mechanism of the Oxidative Regeneration of Carbonyl Compounds from Oximes by Pyridinium Fluorochromate. Reaction Kinetics and Catalysis Letters 71, 343–347 (2000). https://doi.org/10.1023/A:1010391529810

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  • DOI: https://doi.org/10.1023/A:1010391529810

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