Abstract
This paper reports on synthesis and investigation of columnar mesophases of the new members of the homologous series of nitro and amino derivatives of hexaalkoxytriphenylenes, whose mesomorphism was predicted earlier. The forecast is in good agreement with the experimental data. The effect of the introduction of the donor and acceptor groups into the central fragment of triphenylene on the phase transition temperature, texture, and range of existence of columnar mesophases is examined. The predicting ability of the molecular parameters suggested previously for the series under analysis is discussed. It is found that introduction of a nitro group, which is a strong electron acceptor, into the central fragment of triphenylene lowers the melting temperature of the compound versus its analog and does not promote columnar mesomorphism in the lower nonmesomorphous homologs. At the same time, this slightly expands the range of existence of the mesophase in higher homologs.
Similar content being viewed by others
References
S. Chandrasakhar, B. K. Shadashiva, and K. A. Suresh, Pramana, 9, 471-480 (1977).
N. Boden, R. J. Bushby, and A. N. Cammidge, Liq. Cryst., 18, No. 4, 673-676 (1995).
N. Boden, R. J. Bushby, and A. N. Cammidge, Mol. Cryst. Liq. Cryst., 260, 307-313 (1995).
O. B. Akopova, A. A. Bronnikova, A. Kruvchinskii, et al., Zh. Strukt. Khim., 39, No. 3, 464-472 (1998).
E. M. Averianov, Pisma Zh. Ėksp. Teor. Fiz., 61, No. 10, 796-801 (1995).
E. M. Averianov, ibid., 63, No. 1, 29-32 (1996).
E. M. Averianov, Zh. Ėksp. Teor. Fiz., 110, No. 5, 1820-1840 (1996).
E. M. Averianov, Zh. Strukt. Khim., 38, No. 1, 90-97 (1997).
O. B. Akopova and A. M. Shabysheva, USSR Patent No. 1622363, Byull. Izobr., No. 3 (1991).
C. Destrade, N. H. Tinh, H. Gasparoux, et al., Mol. Cryst. Liq. Cryst., 71, 111-135 (1981).
O. B. Akopova, V. I. Bobrov, and Yu. G. Erykalov, Zh. Fiz. Khim., 64, 1460-1471 (1990).
O. B. Akopova, L. S. Shabyshev, and L. V. Zhukova, ibid., 69, 96-100 (1995).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zemtsova, O.V., Syromyatnikova, O.K., Kotovich, L.N. et al. Synthesis and Investigation of Polysubstituted Triphenylenes with a Predictable Type of Mesomorphism. Journal of Structural Chemistry 42, 38–42 (2001). https://doi.org/10.1023/A:1010411804065
Issue Date:
DOI: https://doi.org/10.1023/A:1010411804065