Abstract
The perovskite oxide, LaFeO3, was synthesized by three different preparation methods i.e., the calcination of a mixture of La2O3 and Fe2O3 (La-Fe-O), a co-precipitated precursor (La-Fe-OH), La(OH)3 and Fe(OH)3, and a heteronuclear complex (La-Fe-CN), La[Fe(CN)6] · 5H2O. The obtained powders were characterized by thermogravimetric analysis, powder X-ray diffraction, electron microprobe analysis, specific surface area measurement and scanning electron microscopy. The formation of LaFeO3 is clearly recognized for La-Fe-O, La-Fe-OH and La-Fe-CN at calcining temperatures above 1000, 800 and 600°C, respectively. The mean particle diameter of La-Fe-CN calcined at 600°C for 2 hours was 30 nm. The LaFeO3 perovskite oxide powder obtained by the thermal decomposition of La-Fe-CN was most uniform on an atomic level and the nanosized LaFeO3 powder was obtained at low temperatures. Furthermore, the sinterability was good.
Similar content being viewed by others
References
T. Hibino, S. Wang, S. Kakimoto and M. Sano, Solid State Ionics 127 (2000) 89.
T. Hibino, A. Hashimoto, T. Inoue, J. Tokuno, S. Yoshida and M. Sano, Science 288 (2000) 203.
R. J. Bell, G. J. Millar and J. Drennan, Solid State Ionics 131 (2000) 211.
R. Mochinaga, T. Yamasaki and T. Arakawa, Sensors and Actuators B 66 (2000) 232.
N. Sakai, T. Kawada, H. Yokokawa and M. Dokiya, J. Ceram. Soc. Japan 101 (1993) 1248.
P. Gordes, N. Christiansen, E. J. Jensen and J. Villadsen, J. Mater. Sci. 30 (1995) 1053.
M. Uehara, K. Takahashi, T. Asaka and S. Tsutsumi, J. Ceram. Soc. Japan 106 (1998) 1248.
S. Nakayama, M. Sakamoto, K. Matsuki, Y. Okimura, R. Ohsumi, Y. Nakayama and Y. Sadaoka, Chem. Lett. 1992, p2145.
Y. Sadaoka, H. Aono, E. Traversa and M. Sakamoto, J. Alloys Comp. 278 (1998) 135.
Y. Kotera, T. Saito and M. Terada, Bull. Chem. Soc. Japan 36 (1963) 195.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Nakayama, S. LaFeO3 perovskite-type oxide prepared by oxide-mixing, co-precipitation and complex synthesis methods. Journal of Materials Science 36, 5643–5648 (2001). https://doi.org/10.1023/A:1012526018348
Issue Date:
DOI: https://doi.org/10.1023/A:1012526018348