Abstract
Manganese(II) and manganese(IV) oxides are effective oxidants for the reaction of oxidative carbonylation of aromatic hydrocarbons proceeding at 0.1-1.5 MPa of CO and 20-100°C in trifluoroacetic acid and its anhydride and catalysed by Pd and Rh compounds. Under these conditions up to 9000 moles of aromatic acid is formed per 1 g-at of platinum. With rhodium catalyst instead of the palladium in the case of toluene content of p-toluic acid in the target product increases from 50 to 90%. Carbonylation of biphenyl at 0.1 MPa of CO and 20°C leads toformation of about 15% of fluorenone together with 4-phenylbenzoic acid (60%).
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Kalinovskii, I.O., Pogorelov, V.V., Gelbshtein, A.I. et al. Oxidative Carbonylation of Aromatic Hydrocarbons in the System Containing Pd or Rh Compound, Trifluoroacetic Acid and Its Anhydride, and MnO2 or Mn2O3. Russian Journal of General Chemistry 71, 1457–1462 (2001). https://doi.org/10.1023/A:1013970406482
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DOI: https://doi.org/10.1023/A:1013970406482