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The Oxidation of Organic Compounds in the Troposphere and their Global Warming Potentials

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Abstract

Oxidation by hydroxyl radicals is the main removal process for organic compounds in the troposphere. This oxidation acts as a source of ozone and as a removal process for hydroxyl and peroxy radicals, thereby reducing the efficiency of methane oxidation and promoting the build-up of methane. Emissions of organic compounds may therefore lead to the build-up of two important radiatively-active trace gases: methane and ozone. Emission pulses of 10 organic compounds were followed in a global 3-D Lagrangian chemistry-transport model to quantify their indirect greenhouse gas impacts through changes induced in the tropospheric distributions of methane and ozone. The main factors influencing the global warming potentials of the 10 organic compounds were found to be their spatial emission patterns, chemical reactivity and transport, molecular complexity and oxidation products formed. The indirect radiative forcing impacts of organic compounds may be large enough that ozone precursors should be considered in the basket of trace gases through which policy-makers aim to combat global climate change.

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Authors and Affiliations

  1. Climate Research Division, Meteorological Office, Bracknell, U.K

    W. J. Collins & R. G. Derwent

  2. Hadley Centre for Climate Prediction and Research, Meteorological Office, Bracknell, U.K

    C. E. Johnson

  3. Department of Meteorology, University of Edinburgh, Edinburgh, U.K

    D. S. Stevenson

Authors
  1. W. J. Collins
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  2. R. G. Derwent
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  3. C. E. Johnson
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  4. D. S. Stevenson
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Collins, W.J., Derwent, R.G., Johnson, C.E. et al. The Oxidation of Organic Compounds in the Troposphere and their Global Warming Potentials. Climatic Change 52, 453–479 (2002). https://doi.org/10.1023/A:1014221225434

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