Abstract
Mononuclear palladium(II) complexes containing both pyrazole-type ligands and thiocyanate, of general formula [Pd(SCN)2(L)2] {L = pyrazole (HPz) and 1-phenyl-3-methylpyrazole (phmPz)} have been prepared and characterized by elemental analysis, i.r. and n.m.r. spectroscopy and by single crystal X-ray diffraction methods. The Pd atom in these structures lies on the crystallographic inversion center; in a square-planar coordination geometry made by two sulfur and two nitrogen atoms of the ligands, both in trans positions.
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Godoy Netto, A.V., Frem, R.C., Mauro, A.E. et al. Crystallographic and spectroscopic studies on palladium(II) complexes containing pyrazole and thiocyanate ligands. Transition Metal Chemistry 27, 279–283 (2002). https://doi.org/10.1023/A:1014884601346
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DOI: https://doi.org/10.1023/A:1014884601346