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Synthesis of dichloro derivatives of linear and cyclic permethyloligosilanes and cyclolinear permethylpolysilane-siloxanes and permethylpolyoxysilane based on them

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Abstract

The reactions of dodecamethylcyclohexasilane with chlorides of I, II, IV—VI, and VIII Group metals were studied as a promising approach to the synthesis of functional oligosilanes. When cyclohexasilane reacts with metal chlorides without a solvent at elevated temperatures, the process is intensified and, in some cases, the selectivity of formation of chloro derivatives of linear and cyclic permethyloligosilanes increases. The cyclolinear permethylpolysilane-siloxanes were prepared by heterofunctional polycondensation of the resulting oligosilanes with bifunctional cyclic and linear permethyloligosiloxanes. Cyclolinear permethylpolyoxysilane was synthesized for the first time by the reaction of 1,3-dihydroxycyclohexasilane with 1,3-dichlorohexamethyltrisilane.

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Authors and Affiliations

  1. Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. I. Chernyavskii, D. Yu. Larkin & N. A. Chernyavskaya

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  1. A. I. Chernyavskii
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  2. D. Yu. Larkin
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  3. N. A. Chernyavskaya
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Chernyavskii, A.I., Larkin, D.Y. & Chernyavskaya, N.A. Synthesis of dichloro derivatives of linear and cyclic permethyloligosilanes and cyclolinear permethylpolysilane-siloxanes and permethylpolyoxysilane based on them. Russian Chemical Bulletin 51, 175–180 (2002). https://doi.org/10.1023/A:1015094621119

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