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Metalorganic Chemical Vapor Deposition of Antimony Oxide Films on Semiconductor Substrates

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Abstract

The growth kinetics of oxide films on silicon and gallium arsenide substrates were studied, using alkyl and alkoxide metalorganic precursors (triethylantimony, tripropylantimony, antimony butoxide, and antimony tri-β-aminoethoxide). The effect of thermal annealing on the microstructure and properties of the films was examined. Analysis of the deposition kinetics, composition, and properties of the films demonstrates that metalorganic chemical vapor deposition in an oxidizing atmosphere, using antimony butoxide or triethylantimony as a precursor, enables the growth of insulating layers on Si and GaAs at low temperatures (130–300°C).

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REFERENCES

  1. Razuvaev, G.A., Grabov, B.G., Domrachev, G.A., and Salamarin, B.A., Metalloorganicheskie soedineniya v elektronike (Metalorganic Compounds in Electronics), Moscow: Nauka, 1972.

    Google Scholar 

  2. Wilmsen, C.W., Kee, R.W., Wager, J.F., and Stunnard, I., Interface Formation of Deposited Insulator Layers on GaAs and InP, Thin Solid Films, 1979, vol. 64, no. 1, pp. 49–55.

    Google Scholar 

  3. Powell, C., Oxley, J., and Blocher, J., Jr., Vapor Deposition, New York: Academic, 1967. Translated under the title Osazhdenie iz gazovoi fazy, Moscow: Atomizdat, 1970.

    Google Scholar 

  4. Anokhin, B.G., Balandina, L.P., and Zhurkina, E.M., Deposition of Alumina Films, Materialy II vsesoyuznogo soveshchaniya po metalloorganicheskim soedineniyam dlya polucheniya metallicheskikh i okisnykh pokrytii (Proc. II All-Union Conf. on the Application of Metalorganic Precursors in the Preparation of Metallic and Oxide Coatings), Moscow: Nauka, 1977, pp. 56–57.

    Google Scholar 

  5. Vishnyakov, B.A., Vishnyakova, Z.P., and Pavlova, Z.V., Properties of Al2O3 Films Produced under Electron Irradiation, Izv. Akad. Nauk SSSR, Neorg. Mater., 1972, vol. 8, no. 11, pp. 185–186.

    Google Scholar 

  6. Zaitsev, N.A., Misyurev, E.M., and Pavlov, S.P., Effect of the Starting Aluminum Isopropoxide on the Properties of Al2O3 Films, Elektron. Tekh., Ser. 6: Mater., 1976, no. 8, pp. 102–104.

  7. Barybin, A.A., Tomilin, V.I., and Kempel', V.A., A System for Deposition of Thin Al2O3 Films, Prib. Tekh.Eksp., 1975, no. 3, pp. 238–239.

  8. Razuvaev, G.A., Gribov, B.N., Domrachev, G.A., et al., Osazhdenie plenok i pokrytii razlozheniem metalloorganicheskikh soedinenii (Deposition of Films and Coatings via Decomposition of Metalorganic Precursors), Moscow: Nauka, 1981.

    Google Scholar 

  9. Polyakov, S.M. and Baryshnikov, Yu.Y., Mechanism of Solid-Phase Formation during Thermal Decomposition of Aluminum Triisobutoxide, VI Vsesoyuznoe soveshchanie po primeneniyu metalloorganicheskikh soedinenii dlya polucheniya neorganicheskikh pokrytii i materialov (VI All-Union Conf. on the Application of Metalorganic Precursors in the Preparation of Inorganic Coatings and Materials) (Nizhni Novgorod, 1991), Moscow: Nauka, 1991, p. 21.

    Google Scholar 

  10. Kocheshkov, K.A., Skoldinov, A.P., and Zemlyanskii, I.N., Metody elementoorganicheskoi khimii. Sur'ma, vismut (Methods of Organoelement Chemistry: Antimony and Bismuth), Moscow: Nauka, 1976.

    Google Scholar 

  11. Samsonov, G.V., Phiziko-khimicheskie svoistva okislov: Spravochnik (Physicochemical Properties of Oxides: A Handbook), Moscow: Nauka, 1969.

    Google Scholar 

  12. Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, Chichester: Wiley, 1986.Translated under the title IK-spektry i spektry KR neorganicheskikh i koordinatsionnykh soedinenii, Moscow: Mir, 1991.

    Google Scholar 

  13. Mittova, I.Ya., Ponomareva, N.I., and Malykhina, T.S., Thermal Oxidation of GaAs in the Presence of SbCl3 and BiCl3, Izv. Akad. Nauk SSSR, Neorg. Mater., 1986, vol. 22, no. 6, pp. 893–896.

    Google Scholar 

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Mittov, O.N., Ponomareva, N.I. & Mittova, I.Y. Metalorganic Chemical Vapor Deposition of Antimony Oxide Films on Semiconductor Substrates. Inorganic Materials 38, 576–581 (2002). https://doi.org/10.1023/A:1015861418396

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