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Electrochemical and Corrosion Behavior of Dimensionally Stable Anodes in Chlorate Electrolysis: Efficiency of the Sodium Chlorate Production at Elevated Temperatures

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Abstract

The electrochemical and corrosion behavior of dimensionally stable anodes in chlorate electrolysis is analyzed. The current efficiency (CE) for active chlorine and sodium chlorate is studied at 90°C as a function of the electrolysis duration, dichromate concentration, and solution pH. Effect of interruptions and decrease in the current on CE for the target product is examined. On average, the interruptions can diminish CE by 10–15%.

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REFERENCES

  1. Kokoulina, D.V. and Krishtalik, L.I., Elektrokhimiya, 1971, vol. 7, p. 346.

    Google Scholar 

  2. Kheifets, L.I., Gol'dberg, A.B., and Mazanko, A.F., Itogi Nauki Tekh., Ser. Elektrokhimiya, 1983, p. 244.

  3. Yakimenko, L.M. and Seryshev, G.A., Elektrokhimicheskii sintez neorganicheskikh soedinenii (Electrochemical Synthesis of Inorganic Compounds), Moscow: Khimiya, 1984, p. 35.

    Google Scholar 

  4. Gorodetskii, V.V., Evdokimov, S.V., and Kolotyrkin, Ya.M., Itogi Nauki Tekh., Ser. Elektrokhimiya, 1990, vol. 34, p. 84.

    Google Scholar 

  5. Evdokimov, S.V., Elektrokhimiya, 1999, vol. 35, p. 202.

    Google Scholar 

  6. Evdokimov, S.V., Elektrokhimiya, 1999, vol. 35, p. 367.

    Google Scholar 

  7. Klement'eva, V.S., Cand. Sci. (Chem.) Dissertation, Moscow, GosNIIKhlorProekt, 1984.

    Google Scholar 

  8. Eberil', V.I., Fedotova, N.S., and Novikov, E.A., Elektrokhimiya, 1997, vol. 33, p. 610.

    Google Scholar 

  9. Eberil', V.I., Fedotova, N.S., and Novikov, E.A., Elektrokhimiya, 1997, vol. 33, p. 713.

    Google Scholar 

  10. Chizmadzhev, Yu.A. and Chirkov, Yu.G., Kinetika slozhnykh elektrokhimicheskikh reaktsii (The Kinetics of Complex Electrochemical Reactions), Moscow: Nauka, 1981, p. 284.

    Google Scholar 

  11. Elina, L.M., Gitneva, V.M., Uzbekov, A.A., and Klement'eva, V.S., Khim. Prom-st., Ser. Khlor. Prom-st., 1980, no. 3, p. 8.

  12. Novikov, E.A. and Eberil', V.I., Elektrokhimiya, 1997, vol. 33, p. 620.

    Google Scholar 

  13. Gorodetskii, V.V., Neburchilov, V.A., and Pecherskii, M.M., Elektrokhimiya, 1994, vol. 30, p. 1013.

    Google Scholar 

  14. Eberil', V.I., Dobrov, Yu.V., Novikov, E.A., and Fedotova, N.S., Elektrokhimiya, 1997, vol. 33, p. 617.

    Google Scholar 

  15. Elina, L.M., Gitneva, V.M., and Timokhina, L.I., Khim. Prom-st., Ser. Khlor. Prom-st., 1983, no. 5, p. 1.

  16. Gorodetskii, V.V., Pecherskii, M.M., Yanke, V.B., et al., Elektrokhimiya, 1979, vol. 15, p. 559.

    Google Scholar 

  17. Bune, N.Ya., Pecherskii, M.M., and Losev, V.V., Elektrokhimiya, 1975, vol. 11, p. 1382.

    Google Scholar 

  18. Skripchenko, V.I., Drozdetskaya, E.P., and Il'in, K.G., Zh. Prikl. Khim. (Leningrad), 1975, vol. 48, p. 68.

    Google Scholar 

  19. Il'in, K.G. and Skripchenko, V.I., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1964, vol. 7, p. 572.

    Google Scholar 

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  1. Russian Federation Scientific Center, “Karpov Research Institute of Physical Chemistry,”, ul. Vorontsovo pole 10, Moscow, 103064, Russia

    S. V. Evdokimov

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  1. S. V. Evdokimov
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Evdokimov, S.V. Electrochemical and Corrosion Behavior of Dimensionally Stable Anodes in Chlorate Electrolysis: Efficiency of the Sodium Chlorate Production at Elevated Temperatures. Russian Journal of Electrochemistry 37, 363–370 (2001). https://doi.org/10.1023/A:1016669821615

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