Abstract
A microscopic, modelistic approach was carried out to elucidate the electrochemical reduction of a nuclear waste solution in a packed bed electrode. The interfacial surface reactions within the packed bed were taken into account and the particle–particle contact resistance through oxide films was found to be big enough to effect the potential distribution throughout the bed. On the basis of equations developed here, the contribution of the resistance of the oxide film to the potential and current distribution throughout the bed was compared with the macroscopic homogeneous approach.
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I. C. Agarwal, A. M. Rochon, H. D. Gesser and A. B. Sparling, Water Res. 18(1984) 227.
D. Golub and Y. Oren, J. Appl. Electrochem. 19 (1989) 311.
M. Matlosz and J. Newman, J. Electrochem. Soc. 133 (1986) 1850.
Y. Sun, W. Xuand K. Scott, Electrochim. Acta 38 (1993) 1753.
J. C. Card, S. E. Lyke and S. H. Langer,J. Appl. Electrochem. 20 (1990) 269.
S. G. Chen, T. Wen and J. H. P. Utley, ibid. 22 (1992) 43.
J. Nanzer, S. Langlois and F. Coeuret, ibid. 23 (1993)471, 477.
P. A. Dykstra, G. H. Kelsall, X. Liu and A. C. C. Tseung, ibid. 19 (1989)697.
B. E. El-Anadouli, M. M. Khader, M. M. Saleh and B. G. Ateya ibid. 21 (1991)166.
J. Qi and R. F. Savinell, ibid. 23 (1993) 873, 887.
J. A, McIntyre,Electrochem Soc. Interface 4(1) (1995) 29.
A. K. P Chu, M. Fleischmann and G. J. Hills,J. Appl. Electrochem. 4 (1974) 323.
R. Alkire and P. K. Ng, J. Electrochem. Soc. 124 (1977) 1220.
G. Kreysa and E. Heitz, Electrochim. Acta 20 (1975)919.
P. Fedkiw and J. Newman, AlChE J. 25 (1979) 1077.
C. Y. Yuh and J.R. Selman, Chem. Eng. Commun. 38 (1985) 135.
S. E. Lyke and S. H. Langer, J.Electrochem. Soc. 138 (1991) 2327.
B. E. ElAnadouli and B. G. Ateya, J Appl.Electrochem. 22 (1992) 277.
K. Scott, Y. P. Sun and W. Xu, in `Topics inElectrochemical Engineering' (edited by J. Newman and R. E. White), PV94-22, The Electrochemical Society Proceedings Series, Pennington, NJ (1994), p. 337.
J. S. Newman and C. W. Tobias, J.Electrochem. Soc. 109 (1962) 1183.
J. O'M. Bockris and J. Kim, J. Electrochem. Soc., inpress.
F. A. L. Dullien, `Porous Media Fluid Transport and Pore Structure', 2nd edn, AcademicPress, San Diego (1992), p. 73.
V. M. M. Lobo and J. L. Quaresma, `Handbook of ElectrolyteSolution', Part B, Elsevier, New York (1989), p.1778, p.1781 and p.1803.
D. A. G. Bruggeman,Ann. Phy. (Germany) 24 (1935) 636.
M. S. El-Genk, D. Louie, E. Bergeron and D. Nfitchell, in `Heat Transfer' (edited by N. M. Farukhi), 79, AlChE Symposium Series 225, New York, (1983) p.256.
F. P. Bowen and D. Tabor, `The Friction and Lubrication of Solids',Clarendon Press, Oxford (1950).
R. Holm, `Electric Contacts', Almquist & Wiksells, Sweden(1946).
A. J. Arvia and D. Posadas, in `Encyclopedia of Electrochemistry of the Elements' vol.3, (edited by A. J. Bard), Marcel Dekker, New York (1975) p.211.
T. P. Barrera and K. Nobe, in, `Topics in Electrochemical Engineering' (edited by J. Newman and R. E. White), PV94-22, The Electrochemical Society Proceedings Series, Pennington, NJ (1994), p.229.
J. 'M. Bockris, A. K.N. Reddy and B. Rao, J. Electrochem. Soc. 113 (1966) 1133.
J. Kim, PhD dissertation,Texas A&M University (1996).
S. Trasatti and G. Lodi, in `Electrodes of Conductive Metallic Oxides'(edited by S. Trasatti), Elsevier, New York (1980), p.301.
J. O'M. Bockris and S. D. Argade,J. Chem. Phys. 50 (1969) 1622.
E. M. Lazarova, Elektrokhimiya 14 (1978)1300.
K. Ogawa, S. Yoshikawa and J. S. Lee, J. Chem. Eng. (Japan) 24 (1991) 788.
D. N. Bennion and J. Newman, J. Appl. Electrochem. 2 (1972) 113.
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Bock, J.O., Kim, J. Effect of contact resistance between particles on the current distribution in a packed bed electrode. Journal of Applied Electrochemistry 27, 890–901 (1997). https://doi.org/10.1023/A:1018493300457
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DOI: https://doi.org/10.1023/A:1018493300457