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Infrared study of H/D isotope exchange reaction of alkanes and Brønsted acidic hydroxyl groups on FER zeolite

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Abstract

H/D isotope exchange between n-alkanes and the acidic OD groups in ferrierite was observed by infrared spectroscopy. The real activation energies were estimated by adding the heats of adsorption to the apparent activation energies, resulting in almost the same value for all n-alkanes. The transition state for the reaction is discussed.

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Authors and Affiliations

  1. Research Laboratory of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503, Japan

    Byongjin Lee, Junko N. Kondo & Kazunari Domen

  2. Department of Science and Engineering, National Science Museum, 3-23-1 Hyakunin-cho, Shinjuku-ku, Tokyo, 169-0073, Japan

    Fumitaka Wakabayashi

Authors
  1. Byongjin Lee
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  2. Junko N. Kondo
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  3. Fumitaka Wakabayashi
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  4. Kazunari Domen
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Lee, B., Kondo, J.N., Wakabayashi, F. et al. Infrared study of H/D isotope exchange reaction of alkanes and Brønsted acidic hydroxyl groups on FER zeolite. Catalysis Letters 59, 51–54 (1999). https://doi.org/10.1023/A:1019047916347

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