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Poisoning of aldol condensation reaction with H2O on acid catalysts

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Abstract

The effect of chemisorbing water on three catalysts previously evaluated in the acetone condensation reaction has been studied. The active sites in that reaction are Lewis acid sites present either on the surface of alumina or of nonframework alumina in zeolites. These sites are poisoned by water and the reaction rate decreases at the pace of the loss of Lewis sites. The stoichiometry of the poisoning reactions is one water molecule per site on alumina and two water molecules per site on nonframework alumina.

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References

  1. L. Kubelkovà and J. Novakovà, Zeolites 11 (1991) 822.

    Article  Google Scholar 

  2. V.A. Bell and H.S. Gold, J. Catal. 79 (1983) 286.

    Article  CAS  Google Scholar 

  3. T. Xu, E.J. Munson and J. Haw, J. Am. Chem. Soc. 116 (1994) 1962.

    Article  CAS  Google Scholar 

  4. A.I. Biaglow, J. Šepa, R.J. Gorte and D. White, J. Catal. 151 (1995) 373.

    Article  CAS  Google Scholar 

  5. A.G. Panov and J.J. Fripiat, J. Catal. 178 (1998) 188.

    Article  CAS  Google Scholar 

  6. P.O. Fritz and J.H. Lunsford, J. Catal. 118 (1989) 85.

    Article  CAS  Google Scholar 

  7. R.A. Beyerlein, G.B. McVicker, L.N. Yacullo and J.J. Ziemiak, in: Proc. Am. Chem. Soc. Meeting, Div. Petrol. Chem., Vol. 31, New York, 1986, p. 190.

    CAS  Google Scholar 

  8. A.G. Pelmenschikov and R.A. van Santen, J. Phys. Chem. 97 (1993) 10678.

    Article  CAS  Google Scholar 

  9. F. Wakabayashi, J.N. Kondo, K. Domen and C. Hirose, J. Phys. Chem. 100 (1996) 1442.

    Article  CAS  Google Scholar 

  10. A.G. Pelmenschikov, J.H.M.C van Wolput, J. Janchen and R.A. van Santen, J. Phys. Chem. 99 (1995) 3612.

    Article  CAS  Google Scholar 

  11. F. Wakabayashi, J.N. Kondo, K. Domen and C. Hirose, Catal. Lett. 38 (1996) 15.

    Article  CAS  Google Scholar 

  12. A. Jentys, G. Warechka, M. Derewinski and J. Lercher, J. Phys. Chem. 93 (1989) 4837.

    Article  CAS  Google Scholar 

  13. L.M. Parker, D.M. Bibby and G.R. Burnus, Zeolites 11 (1991) 293.

    Article  CAS  Google Scholar 

  14. H. Knözinger and P. Ratnasami, Catal. Rev. Sci. Eng. 17 (1978) 1.

    Google Scholar 

  15. D. Coster and J.J. Fripiat, Chem. Mater. 5 (1993) 1204.

    Article  CAS  Google Scholar 

  16. F. Yin, A.L. Blumenfeld, V. Gruver and J.J. Fripiat, J. Phys. Chem. B 101 (1997) 1824.

    Article  CAS  Google Scholar 

  17. D. Coster, A.L. Blumenfeld, V. Gruver and J.J. Fripiat, J. Phys. Chem. 98 (1994) 6201.

    Article  CAS  Google Scholar 

  18. V. Gruver and J.J. Fripiat, J. Phys. Chem. 98 (1994) 8549.

    Article  CAS  Google Scholar 

  19. A.G. Panov and J.J. Fripiat, Langmuir 14 (1998) 3788.

    Article  CAS  Google Scholar 

  20. J.B. Peri, J. Phys. Chem. 69 (1965) 211.

    CAS  Google Scholar 

  21. E. Borello, G.D. Gatta, B. Fubini, C. Morterra and G. Venturello, J. Catal. 35 (1974) 1.

    Article  CAS  Google Scholar 

  22. D.J. Coster, J.J. Fripiat, M. Muscos and A. Auroux, Langmuir 11 (1995) 2615.

    Article  CAS  Google Scholar 

  23. D. FĂrcaşiu, J. Catal. 160 (1996) 309.

    Article  Google Scholar 

  24. S.S. Roginski, in: Adsorption und Katalyse in homogen Oberflächen (Akademie Verlag, Berlin, 1958).

    Google Scholar 

  25. A.G. Panov, V. Gruver and J.J. Fripiat, J. Catal. 168 (1997) 321.

    Article  CAS  Google Scholar 

  26. A.L. Blumenfeld and J.J. Fripiat, J. Phys. Chem. B 101 (1997) 6670.

    Article  CAS  Google Scholar 

  27. L.J. Alvarez, A.L. Blumenfeld and J.J. Fripiat, J. Chem. Phys. 108 (1998) 1784.

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry and Laboratory for Surface Studies, University of Wisconsin-Milwaukee, PO Box 413, Milwaukee, WI, 53201, USA

    A.G. Panov & J.J. Fripiat

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  1. A.G. Panov
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  2. J.J. Fripiat
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Panov, A., Fripiat, J. Poisoning of aldol condensation reaction with H2O on acid catalysts. Catalysis Letters 57, 25–32 (1999). https://doi.org/10.1023/A:1019079011862

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  • DOI: https://doi.org/10.1023/A:1019079011862

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