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Catalytic behavior of vanadium-containing mesoporous silicas in the oxidative dehydrogenation of propane

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Abstract

Three series of vanadium-containing silica catalysts (2–7.6 wt% V) have been prepared by varying the synthesis method. In all cases, conversion values in the oxidative dehydrogenation of propane increase with the temperature, vanadium loading and reducibility. For impregnated and anchored catalysts, a relationship between the selectivity towards propene and the effective acidity, as determined in the dehydration of 2-propanol, can be established.

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Authors and Affiliations

  1. Departamento de Química Inorgánica, Cristalografía y Mineralogía, Facultad de Ciencias, Universidad de Málaga, Campus de Teatinos, 29071, Málaga, Spain

    José Santamaría-González, Joaquín Luque-Zambrana, Josefa Mérida-Robles, Pedro Maireles-Torres, Enrique Rodríguez-Castellón & Antonio Jiménez-López

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  1. José Santamaría-González
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  2. Joaquín Luque-Zambrana
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  3. Josefa Mérida-Robles
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  4. Pedro Maireles-Torres
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  5. Enrique Rodríguez-Castellón
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  6. Antonio Jiménez-López
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Santamaría-González, J., Luque-Zambrana, J., Mérida-Robles, J. et al. Catalytic behavior of vanadium-containing mesoporous silicas in the oxidative dehydrogenation of propane. Catalysis Letters 68, 67–73 (2000). https://doi.org/10.1023/A:1019098428836

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