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Acyl Iodides in Organic Synthesis: I. Reactions with Alcohols

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Abstract

Reaction of acyl iodides RC(O)I (R = Me, Ph) with alcohols R'OH (R' = Me, Et, i-Pr, t-Bu, CH2 = CHCH2, HC≡CCH2) provides in the corresponding organyl iodides R'I. Unlike that 2-chloroethanol and phenol (R' = CH2CH2Cl, Ph) react with RC(O)I in the same way as with acyl chlorides yielding esters RCO2R'. This reaction path occurs partially also with methanol and ethanol.

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Authors and Affiliations

  1. Faworsky Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk, 664033, Russia

    M. G. Voronkov, A. A. Trukhina & N. N. Vlasova

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  1. M. G. Voronkov
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  2. A. A. Trukhina
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  3. N. N. Vlasova
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Voronkov, M.G., Trukhina, A.A. & Vlasova, N.N. Acyl Iodides in Organic Synthesis: I. Reactions with Alcohols. Russian Journal of Organic Chemistry 38, 1576–1578 (2002). https://doi.org/10.1023/A:1022593513898

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  • DOI: https://doi.org/10.1023/A:1022593513898

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