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Molar Volume, Molar Refraction, and Isentropic Compressibility Changes of Mixing at 25°C for the System Ethanol + Methanol + Dibutyl Ether

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Abstract

The densities, refractive indexes, and sound velocities for mixtures of ethanol + methanol + dibutyl ether at 25°C and atmospheric pressure, were determined and used to calculate molar volumes, molar refractions, and isentropic compressibilities. The excess molar volumes and the deviations of molar refractions and isentropic compressibilities from mole fraction and volume fraction averages, respectively, of these properties of the pure components were satisfactorily correlated with the composition data by means of the Redlich–Kister polynomial.

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REFERENCES

  1. I. L. Teng and W. E. Acree Jr., Phys. Chem. Liq. 24, 249 (1992).

    Google Scholar 

  2. J. Singh, I. M. Joshi, and S. C. Sharma, J. Chem. Thermodyn. 25, 1049 (1993).

    Google Scholar 

  3. A. Serna, L. García de la Fuente, J. A. González, J. C. Cobos, and C. Casanova, Fluid Phase Equilib. 110, 361 (1995).

    Google Scholar 

  4. E. Jiménez, C. Franjo, L. Segade, J. L. Legido, and M. I. Paz Andrade, Fluid Phase Equilib. 133, 173 (1997).

    Google Scholar 

  5. J. A. Riddick, W. B. Bunger, and T. Sakano, Organic Solvents, 4th. edn. (Wiley, New York, 1986).

    Google Scholar 

  6. T. M. Aminabhavi, M. Y. Aralaguppi, Sh. B. Harogoppad, and R. H. Balundgi, J. Chem. Eng. Data 38, 31 (1993).

    Google Scholar 

  7. A. Arce, J. Mendoza, J. Martínez-Ageitos, and A. Soto, J. Chem. Eng. Data 41, 724 (1996).

    Google Scholar 

  8. A. Arce, E. Rodil, and A. Soto, J. Chem. Eng. Data 42, 721 (1997).

    Google Scholar 

  9. O. J. Redlich and A. T. Kister, Ind. Eng. Chem. 40, 345 (1948).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemical Engineering, University of Santiago de Compostela, E-15706, Santiago, Spain

    Alberto Arce, Eva Rodil & Ana Soto

Authors
  1. Alberto Arce
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  2. Eva Rodil
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  3. Ana Soto
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Arce, A., Rodil, E. & Soto, A. Molar Volume, Molar Refraction, and Isentropic Compressibility Changes of Mixing at 25°C for the System Ethanol + Methanol + Dibutyl Ether. Journal of Solution Chemistry 27, 911–923 (1998). https://doi.org/10.1023/A:1022611228690

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  • DOI: https://doi.org/10.1023/A:1022611228690

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