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Design and Development of Zeolite-Based Catalytic Processes for Aromatics Production

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Abstract

Processes for the production of xylenes, which occur in an integrated aromatic complex, are discussed. A brief overview of the work carried out at Indian Petrochemicals Corporation Limited for the development of zeolite-based catalytic processes for the production of aromatics is presented. This includes xylene isomerization, transalkylation and disproportionation of C7 and C9 aromatics for maximization of xylenes, selective disproportionation of toluene and selective alkylation of mono-alkylaromatics to p-dialkylbenzene. Achievements in the commercialization of zeolite-based catalysts and processes for isomerization of m-xylene to p- and o-xylene along with dealkylation of ethylbenzene, and for selective ethylation of ethylbenzene to produce p-diethylbenzene are highlighted.

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References

  1. Mobil Technology Seminar on Mobil Petrochemical Technologies, 15-16 Nov. 1995 (Tata McGraw-Hill, New Delhi).

  2. UOP Technology Conference 2001, New Delhi, India.

  3. T.C. Tsai, S.B. Liu and I. Wang, Appl. Catal A: Gen. 181 (1999) 355.

    Google Scholar 

  4. A.B. Halgeri and J. Das, Catal. Today.

  5. A.B. Halgeri, Proc. PETROTECH-95, Technology Trends in Petroleum Industry, New Delhi, p. 217.

  6. A.B. Halgeri, S. Kumar, R.C. Sharma, R.C. Bhatta and T.S.R. Prasada Rao, European Patent EP 369 078 (1993).

  7. J. Das, Y.S. Bhat, A.I. Bhardwaj and A.B. Halgeri, Appl. Catal. A: Gen. 116 (1994) 71.

    Google Scholar 

  8. J. Das, Y.S. Bhat and A.B. Halgeri, Catal. Lett. 23 (1994) 257.

    Google Scholar 

  9. A.B. Halgeri and J. Das, Appl. Catal. A: Gen. 181 (1999) 347.

    Google Scholar 

  10. M.A. Uguina, J.L. Sotelo, D.P. Serrano and R.V. Grieken, Ind. Eng. Chem. Res. 31 (1992) 1875.

    Google Scholar 

  11. M.A. Uguina, J.L. Sotelo and D.P. Serrano, Appl. Catal. 76 (1991) 183.

    Google Scholar 

  12. D.H. Olson and W.O. Hagg, ACS Symp. Ser. 248 (1984) 275.

    Google Scholar 

  13. M. Niwa, H. Itoh, S. Kato, T. Hattori and Y. Murakami, J. Chem. Soc. Chem. Commun. (1982) 819.

  14. M. Niwa, S. Kato, T. Hattori and Y. Murakami, J. Phys. Chem. 90 (1986) 6233.

    Google Scholar 

  15. G. Paparatto, G. de Alberti, G. Leofanti and M. Padovan, Stud. Surf. Sci. Catal. 44 (1989) 255.

    Google Scholar 

  16. T. Hibino, M. Niwa and Y. Murakami, Zeolites 13 (1993) 518.

    Google Scholar 

  17. I. Wang, C.L. Ay, B.J. Lee and M.H. Chen, Proc. 9th Int. Congress on Catalysis, 1988, p. 324.

  18. C.T. O'Conner, K.P. Moller and H. Manstein, 5th National Indian Symp. on Catalysis and 2nd Conf. of Indo Pacific Catal. Assoc., 23-25 Jan. 2001, National Chemical Laboratory, Pune, India, PL 02.

  19. J. Das, Y.S. Bhat and A.B. Halgeri, Ind. Eng. Chem. Res. 32 (1993) 2525.

    Google Scholar 

  20. J. Das, Y.S. Bhat and A.B. Halgeri, Ind. Eng. Chem. Res. 23 (1994) 246.

    Google Scholar 

  21. J. Das and A.B. Halgeri, unpublished work.

  22. J. Das, Y.S. Bhat and A.B. Halgeri, US Patent Appl. 09/935,991 (2001).

  23. A.B. Halgeri, J. Das, J.C. Gentry, F.M. Lee and T.S.R. Prasada Rao, Proc. PETROTECH-2001, Technology Trends in Petroleum Industry, New Delhi, 2001, p. 71.

    Google Scholar 

  24. Y.S. Bhat, J. Das and A.B. Halgeri, Appl. Catal. A: Gen. 115 (1994) 257.

    Google Scholar 

  25. Y.S. Bhat, J. Das and A.B. Halgeri, Appl. Catal. A: Gen. 122 (1995) 161.

    Google Scholar 

  26. Y.S. Bhat, J. Das and A.B. Halgeri, J. Catal. 155 (1995) 154.

    Google Scholar 

  27. Y.S. Bhat, J. Das, K.V. Rao and A.B. Halgeri, J. Catal. 159 (1996) 368.

    Google Scholar 

  28. Y.S. Bhat, J. Das and A.B. Halgeri, US Patent 5,811,613 (1998).

  29. Y.S. Bhat, J. Das and A.B. Halgeri, Bull. Chem. Soc. Jpn. 69 (1996) 469.

    Google Scholar 

  30. Y.S. Bhat, J. Das and A.B. Halgeri, Indian J. Chem. Tech. 3 (1996) 319.

    Google Scholar 

  31. J. Das and A.B. Halgeri, Appl. Catal. A: Gen. 194-195 (2000) 359.

    Google Scholar 

  32. J. Das, Y.S. Bhat and A.B. Halgeri, Stud. Surf. Sci. Catal. 113 (1998) 447.

    Google Scholar 

  33. Y.S. Bhat, J. Das and A.B. Halgeri, Appl. Catal. A: Gen. 130 (1995) L1.

  34. Y.S. Bhat, J. Das and A.B. Halgeri, Stud. Surf. Sci. Catal. 105 (1997) 1309.

    Google Scholar 

  35. J. Das and A.B. Halgeri, Proc. 3rd Int. Pet. Conf. and Exhibition, PETROTECH-99, New Delhi, p. 75.

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Correspondence to Anand B. Halgeri.

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Das, J., Halgeri, A.B. Design and Development of Zeolite-Based Catalytic Processes for Aromatics Production. Catalysis Surveys from Asia 7, 3–9 (2003). https://doi.org/10.1023/A:1023424422731

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