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Methanol Decomposition and Synthesis Over Palladium Catalysts

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Abstract

Palladium is generally active in the catalytic decomposition and synthesis of methanol. The activity of palladium is largely affected by its support. Cerium oxide is an effective support especially when the catalyst is prepared by the coprecipitation or depositionprecipitation method which leads to a strong interaction between palladium and the support. Cationic palladium species formed in the catalyst are probably active species for both decomposition and synthesis while formation of Pd-O-Ce bonding is rather important in the synthesis reaction.

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Author notes

  1. Wen-Jie Shen

    Present address: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, PO Box 110, Dalian, 116023, P.R. China

Authors and Affiliations

  1. Research Institute of Innovative Technology for the Earth, Soraku-gun, Kyoto 619-0292, Japan

    Yasuyuki Matsumura

  2. National Institute of Advanced Industrial Science and Technology, Midorigaoka, Ikeda, Osaka, 563-8577, Japan

    Wen-Jie Shen

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  1. Yasuyuki Matsumura
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Correspondence to Yasuyuki Matsumura.

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Matsumura, Y., Shen, WJ. Methanol Decomposition and Synthesis Over Palladium Catalysts. Topics in Catalysis 22, 271–275 (2003). https://doi.org/10.1023/A:1023536306007

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