Abstract
Comparison is made between Cu–ZnO and alumina-supported Cu–ZnO as catalysts for the reverse water-gas shift (RWGS) reaction. For both types of catalyst the Cu/Zn ratio has been varied between Cu-rich and Zn-rich compositions. By applying X-ray diffractometry, X-ray line broadening, optical reflectance spectroscopy and other techniques the effects on the structural and physical properties of the hydroxycarbonate precursors, the calcined products and the ultimately derived catalysts are determined. The presence of alumina decreases the crystallite size of the CuO and ZnO particles produced on calcination and at high Cu/Zn ratios increases the dispersion of copper in the final catalyst. The activities of the catalysts for the RWGS reaction at 513K are compared and the most active are shown to be those which are Cu rich (Cu/Zn > 3) and contain alumina as support. The activities of all the catalysts can be rationalized by referring the activity to unit surface area of copper metal.
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References
J.B. Hansen, in: Handbook of Heterogeneous Catalysis, eds. G. Ertl, H. Knozinger and J. Weitkamp, Vol. 4 (VCH, Weinheim, 1997) p. 1856.
K. Kochloefl, in: Handbook of Heterogeneous Catalysis, eds. G. Ertl, H. Knozinger and J. Weitkamp, Vol. 4 (VCH, Weinheim, 1997) p. 1831.
R.G. Herman, K. Klier, G.W. Simmons, B.P. Finn, J.B. Bulko and T.P. Kobylinski, J. Catal. 56 (1979) 407.
K. Klier, Adv. Catal. 31 (1982) 243.
P. Gherardi, O. Ruggeri, F. Trifiro, A. Vaccari, G. Del Piero, G. Manara and B. Notari, in: Preparation of Catalysts III, eds. G. Poncelet, P. Grange and P.A. Jacobs (Elsevier, Amsterdam, 1983) p. 723.
G. Petrini and F. Garbassi, J. Catal. 90 (1984) 113.
C. Busetto, G. Del Piero, G. Manara, F. Trifiro and A. Vaccari, J. Catal. 85 (1984) 260.
S. Gusi, F. Trifiro, A. Vaccari and G. Del Piero, J. Catal. 94 (1985) 120.
R.M. Hoppener, E.B.M. Doesburg and J.J.F. Scholten, Appl. Catal. 25 (1986) 109.
B.S. Rasmussen, P.E. Højlund-Nielsen, J. Villadsen and J.B. Hansen, in: Preparation of Catalysts IV, eds. B. Delmon, P. Grange, P.A. Jacobs and G. Poncelet (Elsevier, Amsterdam, 1987) p. 785.
R.A. Hadden, P.J. Lambert and C. Ranson, Appl. Catal. A 122 (1995) L1.
J.-L. Li and T. Inui, Appl. Catal. A 137 (1996) 106.
G. Petrini, F. Montino, A. Bossi and F. Garbassi, in: Preparation of Catalysts III, eds. G. Poncelet, P. Grange and P.A. Jacobs (Elsevier, Amsterdam, 1983) p. 735.
P.B. Himelfarb, G.W. Simmons, K. Klier and R.G. Herman, J. Catal. 93 (1985) 442.
M.H. Stacey and M.D. Shannon, in: Reactivity of Solids, eds. P. Barret and L.C. Dufour (Elsevier, Amsterdam, 1985) p. 713.
P. Porta, S. De Rossi, G. Ferraris, M. Lo Jacono, G. Minelli and G. Moretti, J. Catal. 109 (1988) 367.
P. Porta, G. Fierro, M. Lo Jacono and G. Moretti, Catal. Today 2 (1988) 675.
G. Sengupta, D.P. Das, M.L. Kundu, S. Dutta, S.K. Roy, R.N. Sahay and R.K. Mishra, Appl. Catal. 55 (1989) 165.
P. Porta, S. De Rossi, G. Ferraris and F. Pompa, Sol. State Ionics 45 (1991) 35.
B.S. Clausen, G. Steffensen, B. Fabius, J. Villadsen, R. Feidenhans'l and H. Topsøe, J. Catal. 132 (1991) 524.
S. Fujita, A.M. Satriyo, G.C. Shen and N. Takezawa, Catal. Lett. 34 (1995) 85.
S. Fujita, M. Usui, H. Ito and N. Takezawa, J. Catal. 157 (1995) 403.
D. Waller, D. Stirling, F.S. Stone and M.S. Spencer, Faraday Disc. Chem. Soc. 87 (1989) 260.
A.Ya. Rozovskii, Yu.B. Kagan, G.I. Lin, E. Slivinskii, S.M. Loktov, G.L. Liberov and A.N. Bashkirov, Kinet. Katal. 17 (1976) 1314.
S. Fujita, M. Usi and N. Takezawa, J. Catal. 134 (1992) 220.
D. Stirling, F.S. Stone and M.S. Spencer, Stud. Surf. Sci. Catal. 75 (1992) 1507.
M.S. Spencer, Catal. Lett. 32 (1995) 8.
T.S. Askgaard, J.R. Nørskov, C.V. Ovesen and P. Stoltze, J. Catal. 156 (1995) 229.
G.I. Lin, K.P. Kotysev and A.Ya. Rozovskii, Stud. Surf. Sci. Catal. 130 (2000) 713.
J.S. Campbell, Ind. Eng. Chem. Proc. Des. Dev. 9 (1970) 588.
G.C. Chinchen and M.S. Spencer, Catal. Today 10 (1991) 293.
F.H. Chapple and F.S. Stone, Proc. Brit. Ceram. Soc. 1 (1964) 45.
S. Roberts, Phys. Rev. 118 (1960) 1509.
A.M. Pollard, M.S. Spencer, R.G. Thomas, P.A. Williams, J. Holt and J.R. Jennings, Appl. Catal. A 85 (1992) 1.
M.S. Spencer, Catal. Lett. 66 (2000) 255.
J.L. Jambor, Geol. Surv. Canad., Report of Activities, Part C, Paper 76-1C (1976).
A.F. Wells, Acta Crystallogr. 4 (1951) 200.
S. Ghose, Acta Crystallogr. 17 (1964) 1051.
D. Stirling and F.S. Stone, Sol. State Ionics 63-65 (1993) 289.
O. Ruggeri, F. Trifiro and A. Vaccari, J. Sol. State Chem. 42 (1982) 120.
L. Lloyd, D.E. Ridler and M.V. Twigg, in: Catalyst Handbook, ed. M.V. Twigg, 2nd edn (Wolfe, London, 1989) p. 283.
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Stone, F.S., Waller, D. Cu–ZnO and Cu–ZnO/Al2O3 Catalysts for the Reverse Water-Gas Shift Reaction. The Effect of the Cu/Zn Ratio on Precursor Characteristics and on the Activity of the Derived Catalysts. Topics in Catalysis 22, 305–318 (2003). https://doi.org/10.1023/A:1023592407825
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DOI: https://doi.org/10.1023/A:1023592407825