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Electrosynthesis of esters of mono- and dioxoalkanoic and alkanedioic acids on the basis of nitro-substituted alkyl carboxylates and cycloalkanones

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Abstract

A one-pot electrochemical method for the synthesis of methyl monooxoalkanoates with the carbonyl group in position 4, methyl dioxoalkanoates with the oxo groups in positions 4,7-, 6,9-, 7,10-, and 12,15, and methyl 4-oxoalkanedioates was developed. This method is based on amperostatic electrolysis in an undivided cell of the salts of esters of nitroalkaniic acids and their adducts with CH2=CHX (X = Ac, CO2Me).

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    Yu. N. Ogibin, A. I. Ilovaiskii, V. M. Merkulova & G. I. Nikishin

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  1. Yu. N. Ogibin
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  2. A. I. Ilovaiskii
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  3. V. M. Merkulova
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  4. G. I. Nikishin
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Ogibin, Y.N., Ilovaiskii, A.I., Merkulova, V.M. et al. Electrosynthesis of esters of mono- and dioxoalkanoic and alkanedioic acids on the basis of nitro-substituted alkyl carboxylates and cycloalkanones. Russian Chemical Bulletin 52, 728–733 (2003). https://doi.org/10.1023/A:1023935629115

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  • DOI: https://doi.org/10.1023/A:1023935629115

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