Abstract
Isotrithionedithiolate complexes Ct n [M(Dmit)2] (Ct = Li, Na, K, Rb, Cs; M = Mn, Fe, Co, Cu, Hg; Dmit2–= isotrithionedithiolate ion; n= 2 for nonoxidized complexes and n≤ 1 for complexes oxidized with excess iodine) were synthesized for the first time by a peculiar method. IR data revealed that the structure and electronic configuration of the complexes are determined by the nature of the outer-sphere cation, the central atom, and by the oxidation number. Experimental data and quantum-chemical calculations (SW Xαin the relativistic approximation) suggest that isotrithionedithiolatoferrates and -cobaltates can be used to produce new synthetic metals. It was shown for the first time that, unlike the known zincates and cadmiates, isotrithionedithiolatomercurates are oxidized without decomposition to give Ct[Hg(Dmit)2] complexes.
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Zinenko, T.N., Starodub, V.A. & Kazachkov, A.R. Metal Isotrithionedithiolates as Synthetic Metals. Russian Journal of Coordination Chemistry 29, 400–407 (2003). https://doi.org/10.1023/A:1024030110596
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DOI: https://doi.org/10.1023/A:1024030110596