Skip to main content
SpringerLink
Log in

Electrochemical synthesis of phosphorus esters from white phosphorus in the presence of copper complexes and ethanol

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

In the presence of white phosphorus the redox potentials of the copper ions change and the potential of the reduction wave of CuI/Cu0 shifts noticeably toward more positive values. The CuI—P4 complex is characterized by a lower value of the electrochemical gap, that is, higher polarizability and reactivity compared to those of the free CuI cation. Phosphorus esters can be synthesized from P4 and ethanol. The latter is in the composition of the copper(ii) complexes, which act as a catalyst-charge mediator.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. Dambrin, M. Villieras, J. Lebreton, L. Toupet, H. Amri, and J. Villieras, Tetrahedron Lett., 1999, 40, 871.

    Google Scholar 

  2. Ya. A. Dorfman, M. M. Aleshkova, G. S. Polimbetova, L. V. Levina, T. V. Petrova, R. R. Abdreimova, and D. M. Doroshkevich, Usp. Khim., 1993, 62, 928 [Russ. Chem. Rev., 1993, 62 (Engl. Transl.)].

    Google Scholar 

  3. Ya. A. Dorfman and R. R. Abdreimova, Zh. Obshch. Khim., 1993, 63, 289 [Russ. J. Gen. Chem., 1993, 63 (Engl. Transl.)].

    Google Scholar 

  4. Ya. A. Dorfman, R. R. Abdreimova, and D. N. Akbaeva, Kinet. Katal., 1995, 36, 103 [Kinet. Catal., 1995, 36 (Engl. Transl.)].

    Google Scholar 

  5. Ya. A. Dorfman, R. R. Abdreimova, and D. M. Doroshkevich, Teor. Eksp. Khim., 1991, 659 [Theor. Exp. Chem., 1991 (Engl. Transl.)].

  6. Ya. A. Dorfman and R. R. Abdreimova, Koord. Khim., 1996, 22, 764 [Russ. J. Coord. Chem., 1996, 22 (Engl. Transl.)].

    Google Scholar 

  7. R. A. Cherkasov, Metalloorg. Khim., 1989, 2, 13 [Organomet. Chem. USSR, 1989, 2 (Engl. Transl.)].

    Google Scholar 

  8. P. M. Bersier, L. Carlsson, and J. Bersier, Top. Curr. Chem., 1994, 170, 113.

    Google Scholar 

  9. E. Leonel, E. Dolem, M. Devaud, P. Paugam, and J.-Y. Nedelec, Electrochim. Acta, 1997, 42, 2125.

    Google Scholar 

  10. M. Pilo, G. Manca, M. A. Zoroddu, and R. Sceber, Inorg. Chim. Acta, 1991, 180, 225.

    Google Scholar 

  11. A. Cinquantini, R. Cini, R. Seeber, and P. Zanello, J. Electroanalyt. Chem., 1981, 121, 301.

    Google Scholar 

  12. P. Zanello, P. A. Vigato, and G. A. Mazzocehin, Transition Met. Chem., 1982, 7, 291.

    Google Scholar 

  13. R. Bhalla, M. Hellivell, R. L. Beddoes, D. Collison, and C. D. Garner, Inorg. Chim. Acta, 1998, 273, 225.

    Google Scholar 

  14. A. Domenech, E. Garcia-Espana, S. V. Luis, V. Marcellino, and J. F. Miravet, Inorg. Chim. Acta, 2000, 299, 238.

    Google Scholar 

  15. E. Franco, E. Lopez-Torres, M. A. Mendiola, and T. Sevilla, Polyhedron, 2000, 19, 441.

    Google Scholar 

  16. T. V. Magdesieva, K. P. Butin, and O. A. Reutov, Usp. Khim., 1988, 57, 1510 [Russ. Chem. Rev., 1988, 57 (Engl. Transl.)].

    Google Scholar 

  17. Yu. G. Budnikova, O. E. Petrukhina, and Yu. M. Kargin, Zh. Obshch. Khim., 1996, 66, 610 [Russ. J. Gen. Chem., 1996, 66 (Engl. Transl.)].

    Google Scholar 

  18. K. P. Butin, V. V. Strelets, and O. A. Reutov, Metalloorg. Khim., 1990, 3, 814 [Organomet. Chem. USSR, 1990, 3 (Engl. Transl.)].

    Google Scholar 

  19. Y. Okamoto, T. Kusano, and S. Takamuku, Bull. Chem. Soc. Jpn., 1988, 61, 3359.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    Yu. H. Budnikova, A. G. Kafiyatullina & O. G. Sinyashin

  2. Institute of Organic Catalysis and Electrochemistry, 142 ul. Kunaeva, 480100, Alma-Ata, Kazakhstan

    R. R. Abdreimova

Authors
  1. Yu. H. Budnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. G. Kafiyatullina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. G. Sinyashin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R. R. Abdreimova
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Budnikova, Y.H., Kafiyatullina, A.G., Sinyashin, O.G. et al. Electrochemical synthesis of phosphorus esters from white phosphorus in the presence of copper complexes and ethanol. Russian Chemical Bulletin 52, 929–938 (2003). https://doi.org/10.1023/A:1024408627802

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1024408627802

Search

Navigation