Abstract
The thermal stability of the food additives Na metabisulphite, Na and K acetates, glutamic and citric acids, respective of the pharmaceuticals nifedipine and acetyl salicylic acid was studied by means of the non-isothermal kinetic (Friedman differential method). The specificity of the thermal decomposition was characterized by identification of the bond to be selective activated due to energy absorption at vibrational level. These bonds were assigned by comparison of calculated wave numbers with the wave number of the IR spectra.
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H. Ferrari, 'Thermal Analysis' ed. R. F. Schwenker and P. D. Garn, Academic Press, New York 1969, Vol. 1, p. 41.
T. Vlase, G. Jurca and N. Doca, Thermochim. Acta, 379 (2001) 65.
P. Budrugeac and E. Segal, Int. J. Chem. Kinetic, 33 (2001) 564.
P. Budrugeac and E. Segal, Thermochim. Acta, 260 (1995) 75.
P. Budrugeac, J. Therm. Anal. Cal., 64 (2001) 821.
P. Budrugeac, J. Therm. Anal. Cal., 66 (2001) 557.
G. Herzberg, 'Molekülspektren und Molekülstruktur. I. Zweiatomige Moleküle', Steinkopff, Dresden 1939.
N. B. Brandt and S. M. Chudinov, 'Electronic Structure of Metals' MIR Publishers, Moskow 1975.
T. Vlase, G. Vlase and N. Doca, J. Therm. Anal. Cal., in press.
R. M. Silverstein, G. Clayton Bassler and T. C. Morrell, 'Spectrometric Identification of the Compound', 5th Ed., Wiley 1995.
N. B. Colthup, L. H. Daly and S. E. Wiberley, 'Introduction to Infrared and Raman Spectroscopy', Academic Press, New York 1964.
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Vlase, T., Vlase, G., Doca, M. et al. Specificity of decomposition of solids in non-isothermal conditions. Journal of Thermal Analysis and Calorimetry 72, 597–604 (2003). https://doi.org/10.1023/A:1024537902405
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DOI: https://doi.org/10.1023/A:1024537902405