Abstract
The review surveys studies aimed at constructing new materials for gas sensors based on nanocrystalline tin dioxide. The influence of doping with various impurities (Pt, Pd, Ru, Rh, Cu, Ni, or Fe) on the composition, microstructure, and electrophysical and sensor properties of nanocrystalline SnO2 was discussed. The conditions for the preparation of powders and thick and thin SnO2 films by the wet chemical method and aerosol pyrolysis of organometallic compounds are reported. The mechanism of interaction of pure and doped nanocrystalline SnO2 with a gas phase was analyzed based on the data from Mossbauer, Auger electron, and X-ray photoelectron spectroscopy and the results of in situ Raman spectroscopy, XANES, and conductivity measurements.
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References
W. Gopel, Sens. Actuators, A, 1996, 56, 83.
D. E. Williams, Sens. Actuators, B, 1999, 57, 1.
N. Yamazoe and N. Miura, in Chemical Sensor Technology, Ed. S. Yamauchi, Kodansha, Tokyo, 1992, 19.
D. Kohl, Sens. Actuators, B, 1990, 1, 158.
N. Yamazoe, Sens. Actuators, B, 1992, 6, 9.
W. Fliegel, G. Behr, J. Werner, and G. Krabbs, Sens. Actuators, B, 1994, 18-19, 474.
I. Matko, M. Gaidi, B. Chenevier, A. Charai, W. Saikaly, and M. Labeau, J. Electrochem. Soc., 2002, 149, H153.
G. K. Boreskov, Kataliz. Voprosy teorii i praktiki. Izbrannye trudy [Catalysis. Theoretical and Practical Problems. Selected Works], Nauka, Novosibirsk, 1987, 536 pp. (in Russian).
L. Abello, B. Bochu, A. Gaskov, S. Kudryavtseva, G. Lucazeau, and M. Rumyantseva, J. Solid State Chem., 1998, 135, 78.
T. Ressler, M. Hagelstein, U. Hatje, and W. Metz, J. Phys. Chem., B, 1997, 101, 6680.
Z. M. Jarzebski and J. P. Marton, J. Electrochem. Soc., 1976, 123, 199C.
J. Mizusaki, H. Koinuma, J. I. Shimoyama, M. Kawasaki, and K. Fueki, J. Solid State Chem., 1990, 8, 443.
C. G. Fonstad and R. H. Rediker, J. Appl. Phys., 1971, 42, 2911.
J. F. McAleer, A. Maignan, P. T. Moseley, and D. E. Williams, J. Chem. Soc., Faraday Trans. 1, 1989, 85, 783.
J. N. Zemel, Thin Solid Films, 1988, 163, 189.
S. Lenaerts, J. Roggen, and G. Maes, Spectrochim. Acta, 1995, 51A, 883.
O. V. Safonova, G. Delabouglise, B. Chenevier, A. M. Gaskov, and M. Labeau, Mater. Sci. Eng., C, 2002, 21, 105.
M. N. Rumyantseva, M. Labeau, J. P. Senateur, G. Delabouglise, M. N. Boulova, and A. M. Gaskov, Mater. Sci. Eng., B, 1996, 41, 228.
M. N. Rumyantseva, M. Labeau, G. Delabouglise, L. I. Ryabova, I. B. Kutsenok, and A. M. Gaskov, J. Mater. Chem., 1997, 7, 1785.
O. V. Safonova, M. N. Rumyantseva, R. I. Kozlov, M. Labeau, G. Delabouglise, L. I. Ryabova, and A. M. Gaskov, Mater. Sci. Eng., B, 2000, 77, 159.
M. N. Rumyantseva, L. I. Ryabova, T. A. Kuznetsova, M. Labeau, G. Delabouglise, and A. M. Gas´kov, Neorg. Mater., 1999, 35, 68 [Inorg. Mater., 1999, 35, 54 (Engl. Transl.)].
M. N. Rumyantseva, A. M. Gaskov, L. I. Ryabova, J. P. Senateur, B. Chenevier, and M. Labeau, Mater. Sci. Eng., B, 1996, 41, 333.
J. L. Pouchou and F. Pichoir, Rech. Aerosp., 1984, 5, 349.
B. Gautheron, M. Labeau, G. Delabouglise, and U. Schmatz, Sens. Actuators, B, 1993, 15-16, 357.
A. V. Tadeev, G. Delabouglise, and M. Labeau, Thin Solid Films, 1999, 337, 163.
H. Gleiter, Acta Mater., 2000, 48, 1.
S. M. Kudryavtseva, A. A. Vertegel, S. V. Kalinin, N. N. Oleynikov, L. I. Ryabova, L. L. Meshkov, S. N. Nesterenko, M. N. Rumyantseva, and A. M. Gaskov, J. Mater. Chem., 1997, 7, 2269.
O. Safonova, I. Bezverkhy, P. Fabritchny, M. Rumyantseva, and A. Gaskov, J. Mater. Chem., 2002, 12, 1174.
Handbook of X-ray Photoelectron Spectroscopy, Eds. C. D. Wagner, W. M. Riggs, L. E. Davis, and G. F. Moulder, Perkin Elmer Co, New York, 1979, 261.
M. S. Hegde and M. Ayyoob, Surf. Sci., 1986, 173, L635.
Y. Nagasawa, T. Choso, T. Karasuda, S. Shimomura, F. Ouyang, K. Tabata, and Y. Yamaguchi, Surf. Sci., 1999, 433-435, 226.
Q. Li, X. Yuan, G. Zeng, and S. Xi, Mater. Chem. Phys., 1997, 47, 239.
W. Epling, C. K. Mount, and G. B. Hoflund, Appl. Surf. Sci., 1998, 134, 187.
D. E. Ramaker, J. Electron. Spectrosc. Relation Phenom., 1994, 66, 269.
R. D. Shannon and C. T. Prewitt, Acta Cryst., 1969, B25, 925.
M. Gaidi, J. L. Hazemann, I. Matko, B. Chenevier, M. Rumyantseva, A. Gaskov, and M. Labeau, J. Electrochem. Soc., 2000, 147, 3131.
M. Labeau, A. M. Gaskov, B. Gautheron, and J. P. Senateur, Thin Solid Films, 1994, 248, 6.
G. B. Hoflund, Chem. Mater., 1994, 6, 562.
C. R. Henry, Surf. Sci. Rep., 1998, 31, 235.
Fiziko-khimicheskie svoistva oksidov. Spravochnik [Physico-chemical Properties of Oxides. Handbook], Ed. G. V. Rumyantseva et al. 1238 Russ.Chem.Bull., Int.Ed., Vol. 52, No. 6, June, 2003 Samsonov, Metallurgiya, Moscow, 1978, 472 pp. (in Russian).
J. O. Nell and H. St. S. O´Neill, Geochim. Cosmochim. Acta, 1996, 60, 2487.
K. T. Jacob, T. Uda, T. H. Okabe, and Y. Waseda, High Temp. Mater. Processes, 2000, 19, 11.
K. T. Jacob, S. Mishra, and Y. Waseda, J. Am. Ceram. Soc., 2000, 83, 1745.
I. Matko, M. Gaidi, J. L. Hazemann, B. Chenevier, and M. Labeau, Sens. Actuators, B, 1999, 59, 210.
J. Tamaki, T. Maekawa, N. Miura, and N. Yamazoe, Sens. Actuators, B, 1992, 9, 197.
S. Manorama, G. Salara Devi, and V. J. Rao, Appl. Phys. Lett., 1994, 64, 3163.
G. Salara Devi, S. Manorama, and V. J. Rao, J. Electrochem. Soc., 1995, 142, 2754.
T. Pagnier, M. Boulova, A. Galerie, A. Gaskov, and G. Lucazeau, Sens. Actuators, B, 2000, 71,134.
T. Pagnier, M. Boulova, A. Galerie, A. Gaskov, and G. Lucazeau, J. Solid State Chem., 1999, 143, 86.
J. C. Irwin, J. Chrzanovski, T. Wei, D. J. Lockwood, and A. Wold, Physica, C, 1990, 166, 456.
J. F. Xu, W. Li, Z. X. Shen, W. S. Li, S. H. Tang, X. R. Ye, D. Z. Jia, and X. Q. Xin, J. Raman Spectrosc., 1999, 30, 413.
S. D. Ross, in The Infrared Spectra of Minerals, Ed. V. C. Farmer, Mineralogical Society Monograph 4, The Mineralogical Society, London, 1974, p. 423.
F. Kh. Chibirova and E. E. Gutman, Zh. Fiz. Khim., 1999, 73, 292 [Russ. J. Phys. Chem., 1999, 73 (Engl. Transl.)].
A. J. F. Boyle, B. S. P. Bunbury, and C. Edwards, Proc. Phys. Soc. London, 1962, 79, 416.
M. I. Afanasov and P. B. Fabrichnyi, Ross. Khim. Zh., 1996, 40, 54 [Mendeleev Chem. J., 1996, 40 (Engl. Transl.)].
B. P. Kryzhanovskii and A. Ya. Kuznetsov, Zh. Fiz. Khim., 1961, 35, 80 [J. Phys. Chem. USSR, 1961, 35 (Engl. Transl.)].
O. V. Safonova, M. N. Rumyantseva, M. Labeau, and A. M. Gaskov, J. Mater. Chem., 1998, 8, 1577.
J. W. Gardner, Semicond. Sci. Technol., 1989, 4, 345.
C. Descorme and D. Duprez, Appl. Catal., A, 2000, 202, 231.
D. Martin and D. Duprez, J. Phys. Chem., 1996, 100, 9429.
C. Canevali, N. Chiondini, F. Marazzoni, and R. Scotti, J. Mater. Chem., 2000, 10, 773.
T. Jirsak, J. Dvorak, and J. A. Rodriguez, Surf. Sci., 1999, 436, L683.
K. D. Gibson, J. I. Colonell, and S. J. Sibener, Surf. Sci., 1999, 443, 125.
G. K. Reeves and H. B. Harrison, IEEE Electron Dev. Lett., 1982, 5, 111.
B. A. Akimov, A. M. Gas´kov, S. E. Podguzova, M. N. Rumyantseva, L. I. Ryabova, M. Labeau, and A. Tadeev, Fiz. Tekhn. Polupr., 1999, 33, 205 [Semiconductors, 1999, 33, 175 (Engl. Transl.)].
B. A. Akimov, A. V. Albul, A. M. Gas´kov, V. Yu. Il´in, M. N. Rumyantseva, L. I. Ryabova, and M. Labeau, Fiz. Tekhn. Polupr., 1997, 31, 400 [Semiconductors, 1997, 31, 335 (Engl. Transl.)].
O. V. Safonova, M. N. Rumyantseva, L. I. Ryabova, M. Labeau, G. Delabouglise, and A. M. Gaskov, Mater. Sci. Eng., B, 2001, 85, 43.
R. B. Vasiliev, L. I. Ryabova, M. N. Rumyantseva, A. M. Gaskov, and B. A. Akimov, Phys. Stat. Sol. (a), 2001, 188, 1093.
B. A. Akimov, A. M. Gas´kov, M. Labeau, M. M. Osipova, M. N. Rumyantseva, and L. I. Ryabova, Vestn. Mosk. Univ., Ser. Fiz. Astron., 1996, 37, 60 [Moscow Univ. Bull., Ser. Phys. Astron., 1996, 37 (Engl. Transl.)].
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Rumyantseva, M.N., Safonova, O.V., Boulova, M.N. et al. Dopants in nanocrystalline tin dioxide. Russian Chemical Bulletin 52, 1217–1238 (2003). https://doi.org/10.1023/A:1024916020690
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DOI: https://doi.org/10.1023/A:1024916020690