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Preparation and Intercalation Reactions of Zn-Sn LDH and Zn-Al-Sn LDH

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Abstract

Layered double hydroxide (LDH) is synthesized conventionally only with divalent and trivalent cations. In this study, Zn-Sn LDH consisting of di- and tetra-valent cations and Zn-Al-Sn LDH consisting of di-, tri- and tetra-valent cations were prepared and reacted with organic monocarboxylic, dicarboxylic and aromatic acids at 60°C. The 003 spacing of the prepared LDH (Zn-Sn-CO3) is 0.67 nm which is smaller compared to that of the usual LDH (Zn-Al-CO3) with 0.76 nm in the case of carbonate anion as the guest. Zn-Al-Sn-CO3 LDH has two 003 spacings i.e., 0.67 and 0.75 nm which belong to Zn-Sn-CO3 and Zn-Al-CO3 LDH, respectively. Analysis by DTA, TG and DTG indicated that the electrostatic force between the Zn-Sn layers and carbonate anions is larger than that of Zn-Al LDH. The carbonate anions in Zn-Sn LDH decomposed at 261°C while in the usual LDH they decomposed at 230–240°C.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Yamagata University, 4-3-16, Jonan, Yonezawa, Yamagata, 992, Japan

    O. Saber & H. Tagaya

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  1. O. Saber
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  2. H. Tagaya
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Saber, O., Tagaya, H. Preparation and Intercalation Reactions of Zn-Sn LDH and Zn-Al-Sn LDH. Journal of Porous Materials 10, 83–91 (2003). https://doi.org/10.1023/A:1026046711532

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