Abstract
Carbon nanofibers are described as a new ultrahigh-strength material, which is superior to both ordinary carbon fibers and other high-strength materials. The place occupied by nanofibers in the classification of carbon materials is shown, and an analysis is made of the relationship between the structure of a fiber and its useful properties, in particular, the strength and tensile modulus. Studies on the synthesis of nanofibers are reviewed. It is shown that the practically important problem of producing nanofibers of maximum possible length must be solved by controlling the temperature conditions of the reaction. The prospects for introducing nanofibers into the market of high-strength and heat-resistant materials are analyzed. The most likely prospect seems to be the partial replacement of polyacrylonitrile-based fibers by nanofibers, first and foremost, in the fields where the requirements for high strength are particularly stringent due to safety reasons.
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References
Inagaki, M., New Carbons: Control of Structure and Functions, Oxford: Elsevier, Sci., 2002.
Sciences of Carbon Materials Marsh, H. Ed., Alicante: Univ. di Alicante, 2000.
Baker, R.T.K. and Harris, P.S., The Formation of Filamentous Carbon, Chemistry and Physics of Carbon Walker, P.L. and Thrower, P.A., Eds., New York: Marcel Dekker, 1978, p. 83.
Carbon Nanotubes, Endo, M., Ed., Oxford: Pergamon, 1996.
Carbon Nanotubes: Preparation and Properties, Ebbesen, T.W., Ed., New York: CRC, 1997.
Dresselhaus, M.S., Dresselhaus, G., and Eklund, P.C., {tiScience of Fullerenes and Carbon Nanotubes}, London: Academic, 1996.
Eletskii, A.V., Carbon Nanotubes, Usp. Fiz. Nauk {dy1997}, vol. 167, no. 9, p. 945.
Rakov, E.G., Nanotubes of Inorganic Substances, Zh. Neorg. Khim., 1999, vol. 44, no. 11, p. 1827.
Zelenskii, E.S., Kuperman, A.M., Gorbatkina, Yu.A., et al., Reinforced Plastics: Modern Construction Materials, {tiRoss. Khim. Zh.}, 2001, vol. 44, no. 2, p. 56.
Guigon, M., Oberlin, A., and Desarmot, G., Microtexture and Structure of Some High-Modulus, PAN-Base Carbon Fibers, Fibre Sci. Tech., 1984, vol. 20, p. 177.
Tibbetts, G.G. and Beetz, C.P., Mechanical Properties of Vapor-Grown Carbon Fibers, J. Phys. D: Appl. Phys., 1987, vol. 20, p. 292.
Oberlin, A., Endo, M., and Koyama, T., Filamentous Growth of Carbon through Benzene Decomposition, {tiJ. Cryst. Growth}, 1976, vol. 32, p. 335.
Endo, M., Vapor-Grown Carbon Fibers, Ph.D. Thesis, Nagoya: Nagoya Univ., 1978.
Endo, M. and Sikata, M., Tanso faiba (Carbon Fibers), {tiOio Butsuri}, 1985, vol. 54, p. 507.
Endo, M., Oberlin, A., and Koyama, T., Structure and Growth Mechanism of Vapor-Grown Carbon Fibers, {tiJpn. J. Appl. Phys., Part 1}, 1977, vol. 16, p. 1519.
Katsuki, H., Matsunaga, K., Egashira, M., and Kawasumi, S., Formation of Carbon Fibers from Naphthalene on Some Sulfur-Containing Substrates, Carbon, 1981, vol. 9, p. 148.
Ishioka, M., Okada, T., and Matsubara, K., Formation of Vapor-Grown Carbon Fibers in Carbon Monoxide‐Carbon Dioxide‐Hydrogen Mixtures: I. Influence of Carrier Gas Composition, Carbon, 1992, vol. 30, p. 859.
Ishioka, M., Okada, T., and Matsubara, K., Formation of Vapor-Grown Carbon Fibers in Carbon Monoxide‐Carbon Dioxide‐Hydrogen Mixtures: II. Influence of Catalyst, {tiCarbon}, 1992, vol. 30, p. 975.
Tibbetts, G.G., Lengths of Carbon Fibers Grown from Iron Catalyst Particles in Natural Gas, J. Cryst. Growth, 1985, vol. 73, p. 431.
Egashira, M., Katsuki, H., Khayasi, K., and Kawasumi, S., Sekubai-no tanso faiba (Catalytic Carbon Fibers), Sekiyu Gakkai Si, 1983, vol. 26, p. 247.
Motojima, S., Hasegawa, I., Kagiya, S., et al., Vapor Phase Preparation of Micro-Coiled Carbon Fibers by Metal Powder Catalyzed Pyrolysis of Acetylene Containing a Small Amount of Phosphorus Impurity, Carbon, 1995, vol. 33, p. 1167.
Motojima, S., Ivanaga, H., and Varadan, V.K., Kabon maikuro koiru (Carbon Microcoils), Homen, 1998, vol. 36, p. 140.
Soneda, Y. and Inagaki, M., Formation and Graphitization of Vapor-Grown Carbon Fibers, Z. Anorg. Allg. Chem, 1992, vol. 610, p. 157.
Imamutdinov, I. and Perekhodtsev, G., Dirty Glass Effect, Ekspert, October 8, 2001, no. 37.
Seible, F., Priestley, N., and Innamorato, D., Earthquake Retrofit of Bridge Columns with Continuous Carbon Fiber Jackets. Report No. ACTT-95/08, Report to Caltrans, Division of Structures, Prepared under the ARPA/TRP Program Agreement No. MDA 972-94-3-0030, San Diego: Univ. Calif., 1998.
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Mordkovich, V.Z. Carbon Nanofibers: A New Ultrahigh-Strength Material for Chemical Technology. Theoretical Foundations of Chemical Engineering 37, 429–438 (2003). https://doi.org/10.1023/A:1026082323244
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DOI: https://doi.org/10.1023/A:1026082323244