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Carbon Nanofibers: A New Ultrahigh-Strength Material for Chemical Technology

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Abstract

Carbon nanofibers are described as a new ultrahigh-strength material, which is superior to both ordinary carbon fibers and other high-strength materials. The place occupied by nanofibers in the classification of carbon materials is shown, and an analysis is made of the relationship between the structure of a fiber and its useful properties, in particular, the strength and tensile modulus. Studies on the synthesis of nanofibers are reviewed. It is shown that the practically important problem of producing nanofibers of maximum possible length must be solved by controlling the temperature conditions of the reaction. The prospects for introducing nanofibers into the market of high-strength and heat-resistant materials are analyzed. The most likely prospect seems to be the partial replacement of polyacrylonitrile-based fibers by nanofibers, first and foremost, in the fields where the requirements for high strength are particularly stringent due to safety reasons.

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References

  1. Inagaki, M., New Carbons: Control of Structure and Functions, Oxford: Elsevier, Sci., 2002.

    Google Scholar 

  2. Sciences of Carbon Materials Marsh, H. Ed., Alicante: Univ. di Alicante, 2000.

    Google Scholar 

  3. Baker, R.T.K. and Harris, P.S., The Formation of Filamentous Carbon, Chemistry and Physics of Carbon Walker, P.L. and Thrower, P.A., Eds., New York: Marcel Dekker, 1978, p. 83.

    Google Scholar 

  4. Carbon Nanotubes, Endo, M., Ed., Oxford: Pergamon, 1996.

    Google Scholar 

  5. Carbon Nanotubes: Preparation and Properties, Ebbesen, T.W., Ed., New York: CRC, 1997.

    Google Scholar 

  6. Dresselhaus, M.S., Dresselhaus, G., and Eklund, P.C., {tiScience of Fullerenes and Carbon Nanotubes}, London: Academic, 1996.

  7. Eletskii, A.V., Carbon Nanotubes, Usp. Fiz. Nauk {dy1997}, vol. 167, no. 9, p. 945.

  8. Rakov, E.G., Nanotubes of Inorganic Substances, Zh. Neorg. Khim., 1999, vol. 44, no. 11, p. 1827.

    Google Scholar 

  9. Zelenskii, E.S., Kuperman, A.M., Gorbatkina, Yu.A., et al., Reinforced Plastics: Modern Construction Materials, {tiRoss. Khim. Zh.}, 2001, vol. 44, no. 2, p. 56.

  10. Guigon, M., Oberlin, A., and Desarmot, G., Microtexture and Structure of Some High-Modulus, PAN-Base Carbon Fibers, Fibre Sci. Tech., 1984, vol. 20, p. 177.

    Google Scholar 

  11. Tibbetts, G.G. and Beetz, C.P., Mechanical Properties of Vapor-Grown Carbon Fibers, J. Phys. D: Appl. Phys., 1987, vol. 20, p. 292.

    Google Scholar 

  12. Oberlin, A., Endo, M., and Koyama, T., Filamentous Growth of Carbon through Benzene Decomposition, {tiJ. Cryst. Growth}, 1976, vol. 32, p. 335.

  13. Endo, M., Vapor-Grown Carbon Fibers, Ph.D. Thesis, Nagoya: Nagoya Univ., 1978.

    Google Scholar 

  14. Endo, M. and Sikata, M., Tanso faiba (Carbon Fibers), {tiOio Butsuri}, 1985, vol. 54, p. 507.

  15. Endo, M., Oberlin, A., and Koyama, T., Structure and Growth Mechanism of Vapor-Grown Carbon Fibers, {tiJpn. J. Appl. Phys., Part 1}, 1977, vol. 16, p. 1519.

  16. Katsuki, H., Matsunaga, K., Egashira, M., and Kawasumi, S., Formation of Carbon Fibers from Naphthalene on Some Sulfur-Containing Substrates, Carbon, 1981, vol. 9, p. 148.

    Google Scholar 

  17. Ishioka, M., Okada, T., and Matsubara, K., Formation of Vapor-Grown Carbon Fibers in Carbon Monoxide‐Carbon Dioxide‐Hydrogen Mixtures: I. Influence of Carrier Gas Composition, Carbon, 1992, vol. 30, p. 859.

    Google Scholar 

  18. Ishioka, M., Okada, T., and Matsubara, K., Formation of Vapor-Grown Carbon Fibers in Carbon Monoxide‐Carbon Dioxide‐Hydrogen Mixtures: II. Influence of Catalyst, {tiCarbon}, 1992, vol. 30, p. 975.

  19. Tibbetts, G.G., Lengths of Carbon Fibers Grown from Iron Catalyst Particles in Natural Gas, J. Cryst. Growth, 1985, vol. 73, p. 431.

    Google Scholar 

  20. Egashira, M., Katsuki, H., Khayasi, K., and Kawasumi, S., Sekubai-no tanso faiba (Catalytic Carbon Fibers), Sekiyu Gakkai Si, 1983, vol. 26, p. 247.

    Google Scholar 

  21. Motojima, S., Hasegawa, I., Kagiya, S., et al., Vapor Phase Preparation of Micro-Coiled Carbon Fibers by Metal Powder Catalyzed Pyrolysis of Acetylene Containing a Small Amount of Phosphorus Impurity, Carbon, 1995, vol. 33, p. 1167.

    Google Scholar 

  22. Motojima, S., Ivanaga, H., and Varadan, V.K., Kabon maikuro koiru (Carbon Microcoils), Homen, 1998, vol. 36, p. 140.

    Google Scholar 

  23. Soneda, Y. and Inagaki, M., Formation and Graphitization of Vapor-Grown Carbon Fibers, Z. Anorg. Allg. Chem, 1992, vol. 610, p. 157.

    Google Scholar 

  24. Imamutdinov, I. and Perekhodtsev, G., Dirty Glass Effect, Ekspert, October 8, 2001, no. 37.

  25. Seible, F., Priestley, N., and Innamorato, D., Earthquake Retrofit of Bridge Columns with Continuous Carbon Fiber Jackets. Report No. ACTT-95/08, Report to Caltrans, Division of Structures, Prepared under the ARPA/TRP Program Agreement No. MDA 972-94-3-0030, San Diego: Univ. Calif., 1998.

    Google Scholar 

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Mordkovich, V.Z. Carbon Nanofibers: A New Ultrahigh-Strength Material for Chemical Technology. Theoretical Foundations of Chemical Engineering 37, 429–438 (2003). https://doi.org/10.1023/A:1026082323244

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