Abstract
The microporous titanosilicate ETS-10 synthesized from gel with following molar composition: 1.0 Na2O: 1.49 SiO2 : 0.2 TiO2 : 0.6 KF : 1.28 HCl : 39.5 H2O was subjected to sorption of radioactive cations 115Cd2+, 204Hg2+, 60Co2+ and 137Cs+ (M) from aqueous solution, in the absence of ionic competition. The uptake of these cations on the ETS-10 was compared by means of the distribution coefficient (Kd) versus contact time and sorption capacity (R) at equilibrium. The FT-IR spectra of M-ETS-10 sorption products exhibit a modification of the absorption band, principally at 381 cm-1.
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E. V. Kvasnikova, E. D. Stukin, V. N. Golosov, N. N. Ivanova, A. V. Panin, Czech. J. Phys., 49(S1) (1999) 181.
D. W. Breck, Zeolite Molecular Sieves, Structure, Chemistry and Use, Wiley, New York, 1974, p. 771.
A. Dyer, Introduction to Zeolite Molecular Sieves, Wiley, New York, 1988, p. 149.
M. J. Zamzow, J. E. Murphy, Separ. Sci. Technol., 27 (1992) 1969.
L. L. Ames, Amer. Mineralog., 45 (1960) 689.
J. D. Sherman, Adsorption and Ion Exchange Separations, AIChE Symp. Ser., 74(179) (1978) 98.
S. M. Kuznicki, US Patent 4 853 202, 1989.
M. W. Anderson, O. Terasaki, T. Ohsuna, A. Philippou, S. P. Mackay, A. Ferreira, J. Rocha, S. Lidin, Nature, 367 (1994) 347.
M. W. Anderson, O. Terasaki, T. Ohsuna, A. Philippou, S. P. Mackay, A. Ferreira, J. Rocha, S. Lidin, Phil. Mag., B71 (1995) 813.
S. M. Kuznicki, EU Patent 0 457 988 A1, 1991.
L. Al-Attar, A. Dyer, R. Blackburn, J. Radioanal. Nucl. Chem., 246 (2000) 451.
L. Al-Attar, A. Dyer, J. Radioanal. Nucl. Chem., 247 (2000) 121.
C. C. Pavel, D. Vuono, A. Nastro, J. B. Nagy, N. Bilba, Stud. Surf. Sci. Catal., 142 (2002) 295.
C. C. Pavel, D. Vuono, L. Catanzaro, P. De Luca, N. Bilba, A. Nastro, J. B. Nagy, Micropor. Mesopor. Mater., 56(2) (2002) 227.
R. Qadeer, J. Hanif, M. Khan, M. Saleem, Radiochim. Acta, 68 (1995) 197.
X. Yang, J-L. Paillaud, H. F. W. J. van Breukelen, H. Kessler, E. Duprey, Micropor. Mesopor. Mater., 46 (2001) 1.
B. Mihailova, V. Valtchev, S. Mintova, L. Konstantinov, Zeolites, 16 (1996) 22.
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Pavel, C.C., Popa, K., Bilba, N. et al. The sorption of some radiocations on microporous titanosilicate ETS-10. Journal of Radioanalytical and Nuclear Chemistry 258, 243–248 (2003). https://doi.org/10.1023/A:1026269217431
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DOI: https://doi.org/10.1023/A:1026269217431