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Controlled Distribution of Solid Catalysts into Two Immiscible Liquid Phases – Synthesis and Catalytic Applications

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Abstract

A new concept for the separation of heterogeneous catalysts is presented. Against gravity, surface modified catalysts are located only in one of two immiscible liquid phases. The catalyst phase can be separated by simple decantation. Advantages of this multiphase system were demonstrated for hydrogenations and CC coupling reactions.

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References

  1. Handbook of Heterogeneous Catalysis, Vol. 5, eds. G. Ertl, H. Knoezinger and J. Weitkamp (Wiley-VCH, Weinheim, 1997).

    Google Scholar 

  2. Aqueous-Phase Organometallic Catalysis: Concepts and Applications, eds. B. Cornils and W.A. Herrmann (Wiley-VCH, Weinheim, 1998).

    Google Scholar 

  3. G.D. Yadav and S.S. Naik, Catal. Today 66 (2001) 345.

    Google Scholar 

  4. R. Ben-Daniel, A.M. Khenkin and R. Neumann, Chem. A Eur. J. 6 (2000) 3722.

    Google Scholar 

  5. W.D. Bossaert, D.E. de Vos, W.M. van Rhijn, J. Bullen, P.J. Grobet and P.A. Jacobs, J. Catal. 182 (1999) 156.

    Google Scholar 

  6. H. Nur, S. Ikeda and B. Ohtani, J. Catal. 204 (2001) 402.

    Google Scholar 

  7. M. Nobis and B. Driessen-Hoelscher, Angew. Chem. Int. Ed. 21 (2001) 3983.

    Google Scholar 

  8. W.P. Pearlman, Tetrahedron Lett. 17 (1967) 1663.

    Google Scholar 

  9. K. Koehler, R.G. Heidenreich, J.G.E. Krauter and J. Pietsch, Chem. A Eur. J. 8 (2002) 622.

    Google Scholar 

  10. M. van der Zon, P.J. Hamersma, E.K. Poels and A. Bliek, Catal. Today 48 (1999) 131.

    Google Scholar 

  11. H. Vinke, P.J. Hamersma and J.M.H. Fortuin, Eng. Sci. 48 (1993) 2197.

    Google Scholar 

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Authors and Affiliations

  1. Anorganisch-chemisches Institut, Technische Universität München, Lichtenbergstraße 4, 85747, Garching, Germany

    Markus Gruber, Michael Wagner, Roland Heidenreich & Klaus Köhler

  2. Degussa AG, Catalysts & Initiators, Rodenbacher Chaussee 4, 63403, Hanau, Germany

    Jürgen G.E. Krauter & N. Coskun

Authors
  1. Markus Gruber
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  2. Michael Wagner
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  3. Roland Heidenreich
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  4. Jürgen G.E. Krauter
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  5. N. Coskun
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  6. Klaus Köhler
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Corresponding author

Correspondence to Klaus Köhler.

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Gruber, M., Wagner, M., Heidenreich, R. et al. Controlled Distribution of Solid Catalysts into Two Immiscible Liquid Phases – Synthesis and Catalytic Applications. Catalysis Letters 94, 177–180 (2004). https://doi.org/10.1023/B:CATL.0000020542.87789.f5

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  • DOI: https://doi.org/10.1023/B:CATL.0000020542.87789.f5

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