Abstract
A method of ammonia temperature-programmed desorption (TPD) for analysis of acidic property of a solid was improved by introduction of a water vapor treatment method and development of a theory for calculation of ammonia adsorption heat from the TPD profile. The improved method was applied to various solid acid catalysts to establish relationships between the acidic properties and catalytic performances for various acid-catalyzed reactions. Here, examples of the applications to some important acid catalysts are reviewed. The exact analysis of acidic property of Y zeolite and its change by such modifications as steaming and ethylenediaminetetraacetic acid (EDTA) treatment gave a new interpretation on the generation of alkane (paraffin) cracking activity on an ultra stable Y (USY) zeolite. The surface density and strength of acid sites on WO3/ZrO2 and SO4 2−/ZrO2 catalysts were determined, and their relations with catalytic activities for Friedel–Crafts type alkylation and skeletal isomerization of alkane were found.
Similar content being viewed by others
References
M. Niwa, M. Iwamoto and K. Segawa, Bull.Chem.Soc.Jpn.59 (1986)3735.
G.L. Woolery, G.H. Kuehl, H.C. Timken and A.W. Chester, Zeolites.19 (1997)288.
G. Bagnasco, J.Catal.159 (1996)249.
H. Igi, N. Katada and M. Niwa in Proceeding of the 12th International Zeolite Conference,M.M.J. Tracy, B.K. Marcus, M.E. Bisher and J.B. Higgins,(eds)(Materials Research Society (Warrendale,1999)p.2643.
T. Miyamoto, N. Katada, J.-H. Kim and M. Niwa, J.Phys. Chem.B 102 (1998)6738.
S.H. Pine, J.B. Hendrickson, D.J. Cram and G.S. Hammond, Organic Chemistry. 4th ed, (McGraw-Hill International Book, New York,1981)p.16.
W.L. Earl, P.O. Fritz, A.A.V. Gibson and J.H. Lunsford, J.Phys. Chem.91 (1987)2091.
F. Lónyi and J. Valyon,Micro-.Mesopor.Mater.47 (2001)293.
M. Niwa and N. Katada, Catal.Surv.Jpn.1 (1997)215.
M. Niwa, N. Katada, M. Sawa and Y. Murakami,J.Phys.Chem. 99 (1995)8812.
R.J. Gorte,Catal.Lett.62 (1999)1.
N. Katada, H. Igi, J.-H. Kim and M. Niwa,J.Phys.Chem.B 101 (1997)5969.
http://www.chem.tottori-u.ac.jp/niwa/tpd/tpd_index.html
D. Barthomeuf, Mater.Chem.Phys.17 (1987)49.
D. Barthomeuf,J.Phys.Chem.97 (1993)10092.
A. Corma,Chem.Rev.97 (1997)2373.
N. Katada, Y. Kageyama and M. Niwa,J.Phys.Chem.B 104 (2000)7561.
N. Katada and T. Takeguchi, Shokubai (Catalysts & Catalysis)44 (2002)119.
Y. Miyamoto, N. Katada and M. Niwa,Micro-.Mesopor.Mater. 40 (2000)271.
K. Okumura, M. Hashimoto, T. Mimura and M. Niwa,J.Catal. 206 (2002)23.
N. Katada, T. Miyamoto, H.A. Begum, N. Naito, M. Niwa, A. Matsumoto and K. Tsutsumi, J.Phys.Chem.B 104 (2000) 5511.
K. Okumura, K. Nishigaki and M. Niwa,Chem.Lett.(1998) 577.
T. Shigeno, K. Inoue, T. Kimura, N. Katada, M. Niwa and K. Kuroda,J.Mater.Chem.13 (2003)883.
N. Katada, S. Kuroda and M. Niwa, Appl.Catal.A:Gen.180 (1999)L1.
N. Katada, T. Doi, T. Shinmura, S. Kuroda and M. Niwa,Stud. Surf.Sci.Catal.145 (2003)197.
N. Katada, H. Fujinaga, Y. Nakamura, K. Okumura, K. Nishigaki and M. Niwa, Catal.Lett.80 (2002)47.
H.G. Karge, V. Dondur and J. Weitkamp,J.Phys.Chem.B 95 (1991)283.
A.I. Biaglow, D.J. Parrillo and R.J. Gorte,J.Catal.144 (1993)193.
C. Guimon, A. Zouiten, A. Boreave, G. Pfister-Guillouzo, P. Schultz, F. Fitoussi and C. Quet,J.Chem.Soc.,Faraday Trans.90 (1994)3461.
M. Kuehne, H.H. Kung and J.T. Miller,J.Catal.171 (1997)293.
F. Yin, A.L. Blumenfeld, V. Gruver and J.J. Fripiat, J.Phys. Chem.B 101 (1997)1824.
A. Boréave, A. Auroux and C. Guimon, Micropor.Mater.11 (1997)275.
T. Masuda, Y. Fujitaka, H. Ikeda, S. Matsushita and K. Hashimoto,Appl.Catal.A:Gen.162 (1997)29.
A. Zecchina, L. Marchese, S. Bordiga, C. Pazé and E. Gianotti, J.Phys.Chem.B 101 (1997)10128.
W. Zhang, E.C. Burckle and P.G. Smirniotis,Micro-.Mesopor. Mater.33 (1999)173.
W.F. Huang, K.J. Hung, D.C. Huang, C.C. Huang and P.K. Tseng,Catal.Lett.59 (1999)213.
S. Kotrel, J.H. Lunsford and H. Knözinger, J.Phys.Chem.B 105 (2001)3917.
C. Mirodatos and D. Barthomeuf,J.Chem.Soc.,Chem. Commun.(1981)39.
R. Carvajal, P.-J. Chu and J.H. Lunsford, J.Catal.125 (1990) 123.
F. Lónyi and J.H. Lunsford, J.Catal.136 (1992)566.
J. Datka, B. Gil, J. Zlamaniec, P. Batamack, J. Fraissard and P. Massiani, Polish J.Chem.73 (1999)1535.
A. Nock and R. Rudham, Zeolites 7 (1987)481.
U. Lohse, B. Parlitz and V. Patzelová, J.Phys.Chem.93 (1989) 3677.
B. Hunger, M. Heuchel, L.A. Clark and R.Q. Snurr, J.Phys. Chem.B 106 (2002)3882.
A. Kotrel, M.P. Rosynek and J.H. Lunsford,J.Phys.Chem.B 103 (1999)818.
N. Katada, Y. Kageyama, K. Takahara, T. Kanai, H.A. Begum and M. Niwa,J.Mol.Catal.A:Chem.211 (2004)119.
A. Kohara, N. Katada and M. Niwa, Stud.Surf.Sci.Catal.135 (2001)341.
H. Matsuura, N. Katada and M. Niwa, Micro-.Mesopor.Mater. 66 (2003)283.
K. Tanabe, M. Itoh, K. Morishige and H. Hattori in Preparation of Catalysts, B. Delmon, P.A. Jacobs and G. Poncelet (eds) (Elsevier, Amsterdam,1976)p.65.
M. Hino, S. Kobayashi and K. Arata, J.Am.Chem.Soc.101 (1979)6439.
M. Hino and K. Arata, J.Chem.Soc.,Chem.Commun.(1988) 1259.
M. Hino and K. Arata,Chem.Lett.(1989)971.
M. Hino and K. Arata,Chem.Lett.(1981)1671.
K. Arata, Adv.Catal.37 (1990)165.
F.R. Chen, G. Coudurier, J.-F. Joly and J.C. Vedrine, J.Catal. 143 (1993)616.
T. Riemer, D. Spielbauer, M. Hunger, G.A.H. Mekhemer and H. Knözinger, J.Chem.Soc.,Chem.Commun.(1994)1181.
T. Riemer and H. Knözinger, J.Phys.Chem.100 (1996)6739.
B. Umansky, J. Engelhardt and W.K. Hall, J.Catal.127 (1991) 128.
F. Babou, B. Bigot and P. Sautet, J.Phys.Chem.97 (1993)11501.
L.M. Kustov, V.B. Kazanski, F. Figueras and D. Tichit, J.Catal. 150 (1994)143.
R.S. Drago and N. Kob, J.Phys.Chem.B 101 (1997)3360.
F. Haase and J. Sauer, J.Am.Chem.Soc.120 (1998)13503.
V. Adeeva, H.-Y. Liu, B.-Q. Xu and W.M.H. Sachtler, Top. Catal.6 (1998)61.
D. Fãrcaşiu, J.Q. Li and A. Kogelbauer, J.Mol.Catal.A:Chem. 124 (1997)67.
H. Armendariz, C.S. Sierra, F. Figueras, B. Coq, C. Mirodatos, F. Lefebvre and D. Tichit, J.Catal.171 (1997)85.
C.R. Vera and J.M. Parera, J.Catal.165 (1997)254.
N. Naito, N. Katada and M. Niwa, J.Phys.Chem.B 103 (1999) 7206.
N. Katada, J. Endo, K. Notsu, N. Yasunobu, N. Naito and M. Niwa, J.Phys.Chem.B 104 (2000)10321.
M. Niwa, S. Inagaki and Y. Murakami, J.Phys.Chem.89 (1985) 2550.
M. Niwa, K. Suzuki, M. Kishida and Y. Murakami, Appl.Catal. 67 (1991)297.
L.P. Hammett and A.J. Deyrup, J.Am.Chem.Soc.54 (1932) 2721.
Y. Habuta, N. Narishige, K. Okumura, N. Katada and M. Niwa, Catal.Today.78 (2003)131.
N. Narishige and M. Niwa, Catal.Lett.71 (2001)63.
M. Niwa and J. Igarashi, Catal.Today.52 (1999)71.
K. Okumura and M. Niwa, J.Phys.Chem.B 104 (2000)9670.
V. Petranovskii, R.F. Marzke, G. Diaz, A. Gomez, N. Bogdanchikova, S. Fuentes, N. Katada, A. Pestryakov and V. Gurin, Stud.Surf.Sci.Catal.142 (2002)815.
K. Okumura and M. Niwa, Catal.Surv.Jpn.5 (2002)121.
K. Okumura, S. Matsumoto, N. Nishiaki and M. Niwa, Appl. Catal.B:Environ.40 (2003)151.
R. Yoshimoto, K. Okumura and M. Niwa, Catal.Today in press.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Katada, N., Niwa, M. Analysis of Acidic Properties of Zeolitic and Non-Zeolitic Solid Acid Catalysts Using Temperature-Programmed Desorption of Ammonia. Catalysis Surveys from Asia 8, 161–170 (2004). https://doi.org/10.1023/B:CATS.0000038534.37849.16
Issue Date:
DOI: https://doi.org/10.1023/B:CATS.0000038534.37849.16