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Mechanochemical Synthesis of Wüstite, Fe1 – x O, in High-Energy Apparatuses

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Abstract

It is shown that high-energy milling of Fe2O3 + Fe mixtures leads to the formation of nanocrystalline, metastable wüstite Fe1 – x O. Its stoichiometry varies systematically with processing time.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    D. A. Emel'yanov, N. N. Oleinikov & Yu. D. Tret'yakov

  2. Institute of Solid-State Chemistry and Mechanochemistry, Siberian Division, Russian Academy of Sciences, ul. Kutateladze 18, Novosibirsk, 630128, Russia

    K. G. Korolev & M. A. Mikhailenko

  3. Moscow State University, Moscow, 119899, Russia

    A. V. Knot'ko & V. V. Boldyrev

Authors
  1. D. A. Emel'yanov
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  2. K. G. Korolev
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  3. M. A. Mikhailenko
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  4. A. V. Knot'ko
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  5. N. N. Oleinikov
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  6. Yu. D. Tret'yakov
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  7. V. V. Boldyrev
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Emel'yanov, D.A., Korolev, K.G., Mikhailenko, M.A. et al. Mechanochemical Synthesis of Wüstite, Fe1 – x O, in High-Energy Apparatuses. Inorganic Materials 40, 632–635 (2004). https://doi.org/10.1023/B:INMA.0000031998.30974.32

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  • DOI: https://doi.org/10.1023/B:INMA.0000031998.30974.32

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