Abstract
The synthesis of super-microporous aluminosilicate with a pore diameter of 14.6 Å has been achieved, by means of synthesis under specified conditions with a skeletal material comprising TMOS and a small quantity of sodium aluminate, and a conventional alkyl-trimethylammonium halide (C10TMABr) as a template. This super-microporous aluminosilicate has an adsorption capacity of 0.2 ml/g at a relative water vapor pressure of 0.2, and thus is promising as an adsorbent for an adsorption heat-pump.
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References
C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, and J.S. Beck, Nature 359, 710 (1992).
J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.-W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, and J.L. Schlenker, J. Am. Chem. Soc. 114, 10834 (1992).
J.S. Beck, J.C. Vartuli, G.J. Kennedy, C.T. Kresge, W.J. Roth, and S.E. Schramm, Chem. Mater. 6, 1816 (1994).
P.T. Tanev and T.J. Pinnavaia, Chem. Mater. 8, 2068 (1996).
M. Kruk, M. Jaroniec, and A. Sayari, J. Phys. Chem. B 101, 583 (1997).
P.L. Ravikovitch, D. Wei, W.T. Chueh, G.L. Haller, and A.V. Neimark, J. Phys. Chem. B 101, 3671 (1997).
S.A. Bagshaw and A.R. Hayman, Chem. Commun. 533 (2000).
Z.-Y. Yuan,W. Zhou, and L.-M. Peng, Chem. Lett. 1150 (2000).
T. Sun, M.S. Wong, and J.Y. Ying, Chem. Commun. 2057 (2000).
G. Larsen, E. Lotero, and M. Marquez, Chem. Mater. 12, 1513 (2000).
R. Ryoo, I.S. Park, S. Jun, C.W. Lee, M. Kruk, and M. Jaronec, J. Am. Chem. Soc. 123, 1650 (2001).
R. Mokaya, J. Phys. Chem. B 104, 8279 (2000).
S.C. Shen and S. Kawi, J. Phys. Chem. B 103, 8870 (1999).
S. Kawi and S.C. Shen, Mater. Lett. 42, 108 (2000).
E. Bastardo-Gonzalez, R. Mokaya, and W. Jones, Chem. Commun. 1016 (2001).
D.P. Serrano, J. Aguado, J.M. Escola, and E. Garagorri, Chem. Commun. 2041 (2000).
M. Ito, F. Watanabe, and M. Hasatani, Kagaku Kogaku Ronbun 22(1), 163 (1996).
Kazuhisa Yano and Yoshiaki Fukushima, Bull. Chem. Soc. Jpn. 76, 2103 (2003).
P.I. Ravikovitch, D. Wei, W.T. Chueh, G.L. Hallar, and A.V. Neimark, J. Phys. Chem. B 101, 3671 (1997).
M.T. Janicke, C.C. Landry, S.C. Christiansen, S. Birtalan, G.D. Stucky, and B.F. Chemelk, Chem. Mater. 11, 1342 (1999).
E.G. Kodenev, A.N. Shmakov, A.Yu. Derevyankin, O.B. Lapina, and V.N. Romannikov, J. Mol. Catal. A: Chemical 158, 349 (2000).
A. Matsumoto, T. Sasaki, N. Nishimiya, and K. Tsutsumi, Langmuir, 17, 47 (2001).
M. Tather and A. Erdem-Senatalar, Microporous Mesoporous Mater. 34, 23 (2000).
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Yano, K., Fukushima, Y. Synthesis of Super-Microporous Aluminosilicate Having Excellent Water Vapor Adsorption Property as an Adsorbent for an Adsorption Heat-Pump. Journal of Porous Materials 10, 223–229 (2003). https://doi.org/10.1023/B:JOPO.0000011382.11690.08
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DOI: https://doi.org/10.1023/B:JOPO.0000011382.11690.08