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Transetherification of Organosilicon Amines with Cellosolve and Trimethylsilanol

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Abstract

Kinetics of transetherification of (3-aminopropyl)trimethoxysilane, [3-N-(2-aminoethyl)aminopropyl]trimethoxysilane, and (3-aminopropyl)triethoxysilana with Cellosolve and trimethylsilanol were studied. The example of [3-N-(2-aminoethyl)aminopropyl]trimethoxysilane was used to show that the activation energies of the direct and reverse reactions are equal to each other both in the first and in the second stages, which points to independence of the equilibrium constant on temperature (ΔH ≈ 0). With methoxysilanes, the rate constant of the reverse reaction in the second stage of the transetherification with Cellosolve is higher than that of the direct reaction.

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REFERENCES

  1. JP Pat. Appl. 97-143794, Chem. Abstr., 1999, vol. 130, no. 110401.

  2. Pozhidaev, Yu.N., Bol'shakova, S.A., Pestunovich, A.E., Vlasova, N.N., and Voronkov, M.G., Dokl. Ross. Akad. Nauk, 1997, vol. 355, no. 5, p. 653.

    Google Scholar 

  3. Vlasova, N.N., Zhila, G.Yu., Kirillov, A.I., and Voronkov, M.G., Heteroatom. Chem., 1995, vol. 6, no. 2, p. 311.

    Google Scholar 

  4. Kopylov, V.M., Prikhod'ko, P.L., Kireev, V.V., Rudman, E.V., Korshunov, M.A., Mikhlin, V.S., and Kovyazin, V.A., USSR Inventor's Certificate no. 1 122 662, Byull. Isobret., 1984, no. 41

  5. Kovyazin, V.A., Kopylov, V.M., Shkol'nik, M.I., Safrygina, I.A., Demina, N.M., and Ezhova, V.A., RU Patent 2 084 456, Byull. Isobret., 1997, no. 20.

  6. CZ Inventor's Certificate no. 221 786, Ref. Zh. Khim., 1986, 4N77P.

  7. US Patent 4 800 125, Ref. Zh. Khim., 1989, 23T246P.

  8. CZ Inventor's Certificate no. 215 229, Ref. Zh. Khim., 1985, 17N176P.

  9. US Patent 4 410 645, Ref. Zh. Khim., 1984, 24M238P.

  10. US Patent 4 435 474, Ref. Zh. Khim., 1985, 4U246P.

  11. US Patent 4 615 946, Ref. Zh. Khim., 1987, 12T166P.

  12. US Patent 4 704 419, Ref. Zh. Khim., 1988, 14U129P.

  13. RU Patent 2 028 986, Byull. Isobret., 1995, no. 5.

  14. Kovyazin, V.A. and Kopylov, V.M., Zh. Obshch. Khim., 1992, vol. 62, no. 4, p. 842.

    Google Scholar 

  15. Emmanuel', N.M and Knorre, D.G., Kurs khimicheskoi kinetiki (Chemical Kinetics), Mosocow: Vysshaya Shkola, 1969, p. 214.

    Google Scholar 

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Authors and Affiliations

  1. Research Institute of Chemistry and Technology of Organoelement Compounds, Federal State Unitary Enterprise, Moscow, Russia

    V. A. Kovyazin, A. V. Nikitin, V. M. Kopylov & I. B. Sokol'skaya

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  1. V. A. Kovyazin
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  2. A. V. Nikitin
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  3. V. M. Kopylov
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  4. I. B. Sokol'skaya
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Kovyazin, V.A., Nikitin, A.V., Kopylov, V.M. et al. Transetherification of Organosilicon Amines with Cellosolve and Trimethylsilanol. Russian Journal of General Chemistry 73, 1383–1387 (2003). https://doi.org/10.1023/B:RUGC.0000015983.75580.9c

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  • DOI: https://doi.org/10.1023/B:RUGC.0000015983.75580.9c

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