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Functionalization of the Allyl Fragment in (+)-δ-Cadinol

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Abstract

Epoxidation, bromination, and iodination of the double bond in (+)-δ-cadinol under various conditions are accompanied by formation of 1,4- or 1,5-epoxy derivatives. By contrast, vicinal hydroxylation gives rise to “normal” products. Intramolecular cyclization of the resulting vicinal diols was studied.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia

    F. A. Valeev, I. P. Tsypysheva, A. M. Kunakova, O. Yu. Krasnoslobodtseva, O. V. Shitikova & L. V. Spirikhin

  2. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akad. Lavrent'eva 9, Novosibirsk, 630090, Russia

    G. A. Tolstikov

Authors
  1. F. A. Valeev
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  2. I. P. Tsypysheva
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  3. A. M. Kunakova
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  4. O. Yu. Krasnoslobodtseva
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  5. O. V. Shitikova
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  6. L. V. Spirikhin
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  7. G. A. Tolstikov
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Valeev, F.A., Tsypysheva, I.P., Kunakova, A.M. et al. Functionalization of the Allyl Fragment in (+)-δ-Cadinol. Russian Journal of Organic Chemistry 40, 337–345 (2004). https://doi.org/10.1023/B:RUJO.0000034967.56553.3e

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  • DOI: https://doi.org/10.1023/B:RUJO.0000034967.56553.3e

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