Abstract
A review of actually available techniques for the preparation of esters derived form natural oils and fats is presented. A wide choice of catalysts, either homogeneous or heterogeneous, is currently available. This paper evaluates in detail the possibilities for the preparation of fatty acid esters with different alcohols and discusses the criteria for a correct choice. The different problems related to the preparation of esters with low molecular weight monoalcohols and of polyolesters with polyalcohols are discussed. The last part of the paper is devoted to the evaluation of ion-exchange resins as effective catalysts for the preparation of fatty acid esters with low molecular weight monoalcohols.
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References
Oil and Fats International, Biodiesel–Fuelling a change, July 2002, p. 22.
J. Legrand, Performing lubricants and solvents based on oleochemicals, in Proceedings of European Conference Crops for a Green Industry (Gmunden, AT, 6–8 October 1998).
N.O.V. Sontag, Fat splitting and glycerol recovery, in Fatty Acids in Industry, R.W. Johnson and E. Fritz (ed.) (Marcel Dekker Inc., New York, USA, 1988).
E. Twitchell, U.S. Patent 601, 603 (1898); J. Am. Chem. Soc. 22 (1900) 22.
B. Freedman, E.H. Pryde and T.L. Mounts, J. Am. Chem. Soc. 61 (1984) 1638.
M. Mittelbach and B. Trathnigg, Fat Sci. Technol. 92 (1990) 145.
L. Hartman, J. Am. Chem. Soc. 78 (1956) 129.
V. Stanisci, personal communication
Y.M. Choo, K.Y. Cheah, A.N. Ma, A. Halim and A.S.H. Ong, Conversion of crude palm kernel oil into its methyl esters on pilot plant scale, in Proceedings of World Conference Oleochemicals into the 21st Century, T.H. Applewhite (ed.) (American Oil Chem. Society, Champaign, IL, 1990) p. 292.
U. Schuchardt and O.C. Lopes, J. Am. Oil Chem. Soc. 65 (1988) 1940.
R. Sercheli, R.M. Vargas and U. Schuchardt, J. Am. Oil Chem. Soc. 76 (1999) 1207.
U. Schuchardt, R.M. Vargas and G. Gelbard, J. Mol. Catal. 109 (1996) 37.
R. Sercheli, A.L.B. Ferreira, M.C. Guerreiro, R.M. Vargas, R.A. Sheldon and U. Schuchardt, Tetrahedron Lett. 38 (1997) 1325.
S.K.F. Peter, R. Ganswindt, H.P. Neuner and E. Weldner, Eur. J. Lipid Sci. Technol. 104 (2002) 324.
P. Bondioli, L. Inzaghi, G. Postorino and P. Quartuccio, J. Synth. Lub. 15 (1999) 271 (Reprint of original paper published in Riv. It. Sostanze Grasse, 74 (1997) 137).
P. Bondioli, L. Della Bella and A. Manglaviti, Ol. Corps Gras, Lipides 10(2003) 150.
P. Bondioli, Lubricants and Hydraulic Fluids, in Oleochemical Manufacture and Applications, F.D. Gunstone and R.J. Hamilton (eds) (Sheffield Academic Press, Sheffield, UK, 2001).
P. Marchal, C. Masson, Z. Moulongui, M. Delmas and A. Gaset, Revue Française des Corps Gras 32 (1985) 429.
M. Asdih, P. Marchal, Z. Moulongui, R.L. Gharbi, M. Delmas and A. Gaset, Revue Française des Corps Gras 37 (1990) 241.
DIAION–Manual of Ion Exchange Resins and Synthetic Adsorbent, Vol. II (Mitsubishi Chemical Corporation, Tokyo, Japan, 1995) p. 184.
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Bondioli, P. The Preparation of Fatty Acid Esters by Means of Catalytic Reactions. Topics in Catalysis 27, 77–82 (2004). https://doi.org/10.1023/B:TOCA.0000013542.58801.49
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DOI: https://doi.org/10.1023/B:TOCA.0000013542.58801.49