Abstract
THERE has been a lengthy controversy between G. W. Morey1 and A. Dietzel2 concerning the nature of the crystallites in devitrified glass in region B of the phase diagram of the system: SiO2 Na2O CaO (see2). Morey, from microscopic investigations, thought that tridymite was present in this devitrified glass, whereas Dietzel, with the further help of expansion curves, decided in favour of cristobalite. Microscopic work on such a problem is very difficult, especially when dealing with crystallites in crusted in a vitreous mass. On the other hand, expansion curves are quite useless. There are three anomalies in the expansion of pure tridymite. The first occurs about 120° C., the second around 165° C. and the last at 420° C. A solid rod of 36 mm. of glass B does not give any appreciable anomaly of expansion. A rod of the same dimensions made from a powder of this devitrified glass also gives a negative result. X-ray powder analysis on the contrary gives a definite solution of the problem. A devitrified glass of the initial percentage composition: SiO2 78, CaO 12, and Na2O 10 (glass B) gives an unmistakable pattern of tridymite (Co-K-50 m.a.h.).
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References
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M. E. Nahmias, Z. Kr., 85, 355; 1933.
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NAHMIAS, M. X-Ray Investigation of Tridymite-glass. Nature 132, 857–858 (1933). https://doi.org/10.1038/132857c0
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DOI: https://doi.org/10.1038/132857c0
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