Abstract
IT has been shown1,2 from an examination of the polarographic behaviour of some Rh(III)-arsine and phosphine complexes in dimethylformamide (DMF) as solvent that these complexes undergo reaction with the solvent. To elucidate this reaction and to identify the reaction product, an investigation has been undertaken, the results of which are reported here.
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References
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RUSINA, A., VLČEK, A. Formation of Rh(I)-Carbonyl Complex by the Reaction with Some Non-alcoholic, Oxygen-containing Solvents. Nature 206, 295–296 (1965). https://doi.org/10.1038/206295a0
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DOI: https://doi.org/10.1038/206295a0
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