Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Effect of rapid precipitation of dissolved Mn in river water on estuarine Mn distributions

Abstract

ALTHOUGH the general characteristics of estuarine chemical behaviour can be deduced from distributional data1, there is an urgent need for greater understanding of the mechanisms and kinetics of the processes involved to assist the development of precise geochemical cycling models and to allow accurate predictions of the consequences of waste disposal into estuaries and inland waters. Manganese is of particular importance in this respect because, as well as exhibiting pronounced reactivity within estuaries2–4, the highly absorptive properties of particulate and colloidal manganese oxide phases may contribute significantly to the estuarine behaviour of many other trace metals5. We show here how measurements of the effects of suspended particles and salinity on the rate of precipitation of dissolved manganese can lead to an explanation of the temporal and geographical variability in the distribution of dissolved manganese in an estuarine system.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Liss, P. S. in Estuarine Chemistry (eds Burton, J. D, & Liss, P. S.) 93–130 (Academic, London, 1976).

    Google Scholar 

  2. Evans, D. W., Cutshall, N. H., Cross, F. A. & Wolfe, D. A. Est. coastal mar. Sci. 5, 71–80 (1977).

    Article  ADS  CAS  Google Scholar 

  3. Sanders, J. G. Est. coastal mar. Sci. 6, 231–238 (1978).

    Article  ADS  CAS  Google Scholar 

  4. Duinker, J. C. & Nolting, R. F. Netherlands J. Sea Res. 12, 205–223 (1978).

    Article  ADS  CAS  Google Scholar 

  5. Jenne, E. A. in Trace Inorganics in Water (ed. Gould, R. F.) 337–387 (American Chemical Society, Washington, 1968).

    Book  Google Scholar 

  6. McArthur, J. M. Analyt. chim. Acta 93, 77–83 (1977).

    Article  CAS  Google Scholar 

  7. Morgan, J. J. in Principles and Applications of Water Chemistry (eds Faust, S. D. & Hunter, J. V.) 561–624 (Wiley, New York, 1967).

    Google Scholar 

  8. Manheim, F. T. Geochim. cosmochim. Acta 25, 52–71 (1961).

    Article  ADS  CAS  Google Scholar 

  9. Hem, J. D. U.S. Geol. Surv. Wat. Supply Pap. 1667-A (1964).

  10. Hem, J. D. U.S. Geol. Surv. Prof. Pap. 475–C, C216–C217 (1963).

  11. Murray, J. W. Geochim. cosmochim. Acta 39, 505–510 (1975).

    Article  ADS  CAS  Google Scholar 

  12. Morgan, J. J. & Stumm, W. Proc. 2nd Int. Conf. Wat. Pollut. Res., Tokyo 1964, 103–131 (Pergamon, New York, 1965).

    Google Scholar 

  13. Crerar, D. A. & Barnes, H. L. Geochim. cosmochim. Acta 38, 279–300 (1974).

    Article  ADS  CAS  Google Scholar 

  14. Hem, J. D. Geochim. cosmochim. Acta 41, 527–538 (1977).

    Article  ADS  CAS  Google Scholar 

  15. Hem, J. D. Chem. Geol. 21, 199–218 (1978).

    Article  ADS  CAS  Google Scholar 

  16. Festa, J. F. & Hansen, D. V. Est. coastal mar. Sci. 7, 347–359 (1978).

    Article  ADS  Google Scholar 

  17. Holliday, L. M. & Liss, P. S. Est. coastal mar. Sci. 4, 349–353 (1976).

    Article  ADS  CAS  Google Scholar 

  18. Morris, A. W., Mantoura, R. F. C., Bale, A. J. & Howland, R. J. M. Nature 274, 678–680 (1978).

    Article  ADS  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

MORRIS, A., BALE, A. Effect of rapid precipitation of dissolved Mn in river water on estuarine Mn distributions. Nature 279, 318–319 (1979). https://doi.org/10.1038/279318a0

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1038/279318a0

This article is cited by

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing